Nitromethane with Aromatic hydrocarbons (IUPAC SDS Volume 71)

SDS Volume

Volume 71. Nitromethane with Water or Organic Solvents, p 1252

Source Publication

Mulliken, S. P.; Wakeman, R. L.; Recl. Trav. Chim. Pays-Bas, 54, 366-72 (1935).

Conditions:

Room Temp: 257 - 349 $\pu{K}$

Compiler:

V.P. Sazonov

Methodology:

The synthetic method was used. Miscibility was determined in a glass-stoppered tube of 4 mm inside diameter. Equal volumes (0.1 mL) of (1) and (2) were measured into the tube which was then strapped to a thermometer, warmed to 5 or 10 °C above the solubility temperature, mixed well by shaking, and then allowed to cool slowly, still shaking, in a bath of white oil (above 30 °C), water (below 30 °C), or nonfreezing mixture (below 0 °C).

Sample Information:
  1. Not specified.
  2. Some aromatic hydrocarbons(*) obtained from Mr. J. B. Conant, Harvard University; others were purest commercial samples.
Measurement Errors:

Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.

System Components:
  1. Nitromethane $\ce{ CH3NO2 }$ [75-52-5]; NIST WebBook
  2. 1,2,3,4-Tetrahydronaphthalene $\ce{ C10H12 }$ [119-64-2]; NIST WebBook
    1,4-Diethylbenzene $\ce{ C10H14 }$ [105-05-5]; NIST WebBook
    4-Isopropyl methylbenzene $\ce{ C10H14 }$ [99-87-6]; NIST WebBook
    m-Diethylbenzene $\ce{ C10H14 }$ [141-93-5]; NIST WebBook
    sec-Butylbenzene $\ce{ C10H14 }$ [135-98-8]; NIST WebBook
    Butylbenzene $\ce{ C10H14 }$ [104-51-8]; NIST WebBook
    tert-Pentylbenzene $\ce{ C11H16 }$ [2049-95-8]; NIST WebBook
    Cyclohexylbenzene $\ce{ C12H16 }$ [827-52-1]; NIST WebBook
    1,8-Diphenyl-1,3,5,7-octatetraene $\ce{ C20H18 }$ [3029-40-1]; NIST WebBook
    2,4-Dimethyl-3-benzylidenepentane $\ce{ C14H20 }$
    [1,3-Dimethyl-2-(1-methylethyl)-1-butenyl]-benzene $\ce{ C15H22 }$ [100649-45-4]; NIST WebBook
    2,6-Dimethylnaphthalene $\ce{ C12H12 }$ [581-42-0]; NIST WebBook
    1-methyl-4-(4-methylphenyl)benzene $\ce{ C14H14 }$ [613-33-2]; NIST WebBook
    Octahydroanthracene $\ce{ C14H18 }$ [1079-71-6]; NIST WebBook
Experimental Data

Miscibility temperatures of mixtures with equal volumes of nitromethane (1) with aromatic hydrocarbons (c10 - c20) (2)

Aromatic hydrocarbons (C8-C20) $T$ (°C) $T$ ($\pu{K}$) $T$ (°C)
1,2,3,4-Tetrahydronaphthalene (link to XML output link to JSON output link to JSON-LD output) -16257203
1,4-Diethylbenzene (link to XML output link to JSON output link to JSON-LD output) -5268182
4-Isopropyl methylbenzene (link to XML output link to JSON output link to JSON-LD output) -4269176.5
m-Diethylbenzene (link to XML output link to JSON output link to JSON-LD output) -3270181
sec-Butylbenzene (link to XML output link to JSON output link to JSON-LD output) -1272174
Butylbenzene (link to XML output link to JSON output link to JSON-LD output) 4277182
tert-Pentylbenzene (link to XML output link to JSON output link to JSON-LD output) 14287190
Cyclohexylbenzene (link to XML output link to JSON output link to JSON-LD output) 24297238
1,8-Diphenyl-1,3,5,7-octatetraene (link to XML output link to JSON output link to JSON-LD output) 27300197@ 1.07 kPa
2,4-Dimethyl-3-benzylidenepentane (link to XML output link to JSON output link to JSON-LD output) 34307112@ 1.5 kPa
[1,3-Dimethyl-2-(1-methylethyl)-1-butenyl]-benzene (link to XML output link to JSON output link to JSON-LD output) 49322110@ 0.4 kPa
2,6-Dimethylnaphthalene (link to XML output link to JSON output link to JSON-LD output) 62335261
1-methyl-4-(4-methylphenyl)benzene (link to XML output link to JSON output link to JSON-LD output) 69342295
Octahydroanthracene (link to XML output link to JSON output link to JSON-LD output) 76349292