Compilation - Bromobenzene with Water (IUPAC SDS Volume 20)
SDS Volume (26)
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 141
Original Measurements
Donahue, D. J.; Bartell, F. E.; J. Phys. Chem. 1952, 56, 480-4.
Variables:
Room Temp: 25 °C
Prepared by:
Method/Apparatus/Procedure:
A mixture of water and bromobenzene was placed in a glass stoppered flask and shaken intermittently for at least three days in a constant temperature water bath. The water content of the organic phase was established by the Karl Fisher method and the organic content of the aqueous phase was established interferometrically.
Source and Purity of Materials:
- Reagent grade, purified by fractional distillation.
- Purified by distillation.
Estimated Errors:
Ambient temperature: ±0.1 K.
Mass concentration (m/v) (1): ±5% (compiler).
Components:
- Bromobenzene, $\ce{ C6H5Br }$; [108-86-1] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | MR1 (g/kg) | m1 (mol/kg) |
|---|---|---|---|
| 25 | 5.3 x 10-5 | 0.462 | 2.94 x 10-3 |
(a) Calculated by the compiler.
(b) Calculated by F. W. Getzen.
(c) Reported.
