SDS Volume
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 141
Source Publication
Donahue, D. J.; Bartell, F. E.; J. Phys. Chem. 1952, 56, 480-4.
Conditions:
Room Temp: 25 °C
Compiler:
Methodology:
A mixture of water and bromobenzene was placed in a glass stoppered flask and shaken intermittently for at least three days in a constant temperature water bath. The water content of the organic phase was established by the Karl Fisher method and the organic content of the aqueous phase was established interferometrically.
Sample Information:
- Reagent grade, purified by fractional distillation.
- Purified by distillation.
Measurement Errors:
Ambient temperature: ±0.1 K.
Mass concentration (m/v) (1): ±5% (compiler).
System Components:
- Bromobenzene, $\ce{ C6H5Br }$; [108-86-1] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | MR1 (g/kg) | m1 (mol/kg) |
|---|---|---|---|
| 25 | 5.3 x 10-5c | 0.462a | 2.94 x 10-3b |
(a) Calculated by the compiler.
(b) Calculated by F. W. Getzen.
(c) Reported.
