{"compilation": {"title": "Solubility data from IUPAC SDS Volume 20 (page 141) - Bromobenzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Donahue, D. J.; Bartell, F. E.; J. Phys. Chem. 1952, 56, 480-4.", "pubtype": "paper", "url": "https://doi.org/10.1021/j150496a016"}], "system": "Bromobenzene with Water", "substances": [{"constituent": 1, "name": "Bromobenzene", "formula": "C6H5Br", "molweight": 157.008, "casrn": "108-86-1", "inchi": "InChI=1S/C6H5Br/c7-6-4-2-1-3-5-6/h1-5H", "inchikey": "QARVLSVVCXYDNA-UHFFFAOYSA-N", "sample": "Reagent grade, purified by fractional distillation."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Purified by distillation."}], "method": "A mixture of water and bromobenzene was placed in a glass stoppered flask and shaken intermittently for at least three days in a constant temperature water bath. The water content of the organic phase was established by the Karl Fisher method and the organic content of the aqueous phase was established interferometrically.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.3e-05", "significand": "5.3", "exponent": "-5", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "4.62e-01", "significand": "4.62", "exponent": "-1", "sigfigs": "3", "unit": "g/kg"}, {"property": "Molality (1 in 2)", "number": "2.94e-03", "significand": "2.94", "exponent": "-3", "sigfigs": "3", "unit": "mol/kg"}], "supplemental": []}]}, {"series": 2, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "2.9e-03", "significand": "2.9", "exponent": "-3", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (2)", "number": "3.34e-01", "significand": "3.34", "exponent": "-1", "sigfigs": "3", "unit": "g/kg"}, {"property": "Molality (2)", "number": "1.85e-02", "significand": "1.85", "exponent": "-2", "sigfigs": "3", "unit": "mol/kg"}, {"property": "Mole fraction - Liquid (2)", "number": "2.9e-03", "significand": "2.9", "exponent": "-3", "sigfigs": "2", "unit": "1"}], "supplemental": []}]}]}}