SDS Volume (949)

Volume 38. Hydrocarbons in Water and Seawater, Part II, p None

Original Measurements

Mackay, D.; Shiu, W. Y.; J. Chem. Eng. Data. 1977, 22, 399-402.

Variables:

Temperature: 25 °C

Prepared by:

M.C. Haulait-Pirson

Method/Apparatus/Procedure:

A saturated solution of (1) in (2) was vigorously stirred in a 250 mL flask for 24 hrs. and subsequently settled at 25 °C for at least 48 hrs. Then the saturated solution was decanted and filtered and 50-100 mL extracted with approximately 5 mL of cyclohexane in a separatory funnel. After shaking for 2 hrs. the cyclohexane extract was removed for analysis. An Aminco-Browman spectrophotofluorometer (American Instruments Ltd.) was used for analysis. Many details are given in the paper.

Source and Purity of Materials:
  1. Aldrich Chemicals, Eastman Kodak, or K and K Laboratories, commercial highest grade; used as received.
  2. Doubly distilled

Pyrene with Water

Components:

(1) Pyrene, $\ce{ C16H10 }$; [129-00-0] NIST WebBook
(2) Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook

Experimental Values:

The solubility of pyrene in water at 25°C was reported to be 0.135 mg(1) dm-3 sln and x1 = 1.2 × 10-8.
The corresponding mass percent calculated by the compiler is 0.0000135 g(1)/100 g sln.

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