SDS Volume
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 173
Source Publication
Goldman, S.; Ph.D. Dissertation, McGill University, Montreal, Canada 1969, p 84.
Conditions:
Room Temp: 25.0 - 45.06 °C
Compiler:
Methodology:
Equilibrium experiments were carried out in a constant temperature water bath using a stirrer. An equilibration period of at least five days was allowed. The total water content in the organic phase was determined by a Karl Fischer titration. Each reported water solubility was obtained as an average of at least two independent determinations.
Sample Information:
- Distilled.
- Reagent grade, washed with conc. $\ce{H2SO4}$ and with 1 M $\ce{NaHCO3}$ and then fractionally distilled over silica gel.
Measurement Errors:
Ambient temperature: ±0.1 K.
Mass concentration (m/v) (1): ±2%.
System Components:
- Chlorobenzene, $\ce{ C6H5C1 }$; [108-90-7] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | $C_{1}$ (mol/dm3) |
|---|---|---|
| 25 | 2.959 x 10-3c | 0.0290 |
| 35.1 | 4.234 x 10-3c | 0.0411 |
| 45.06 | 5.567 x 10-3c | 0.0535 |
(a) Calculated by F. W. Getzen.
(b) Reported.
(c) Calculated by the compiler.
