{"compilation": {"title": "Solubility data from IUPAC SDS Volume 20 (page 173) - Chlorobenzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Goldman, S.; Ph.D. Dissertation, McGill University, Montreal, Canada 1969, p 84.", "pubtype": "dissertation"}], "system": "Chlorobenzene with Water", "substances": [{"constituent": 1, "name": "Chlorobenzene", "formula": "C6H5C1", "molweight": 112.557, "casrn": "108-90-7", "inchi": "InChI=1S/C6H5Cl/c7-6-4-2-1-3-5-6/h1-5H", "inchikey": "MVPPADPHJFYWMZ-UHFFFAOYSA-N", "sample": "Distilled."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Reagent grade, washed with conc. $\\ce{H2SO4}$ and with 1 M $\\ce{NaHCO3}$ and then fractionally distilled over silica gel."}], "method": "Equilibrium experiments were carried out in a constant temperature water bath using a stirrer. An equilibration period of at least five days was allowed. The total water content in the organic phase was determined by a Karl Fischer titration. Each reported water solubility was obtained as an average of at least two independent determinations.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.959e-03", "significand": "2.959", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Amount concentration (1)", "number": "2.90e-02", "significand": "2.90", "exponent": "-2", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.51e+01", "significand": "3.51", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "4.234e-03", "significand": "4.234", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Amount concentration (1)", "number": "4.11e-02", "significand": "4.11", "exponent": "-2", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "4.506e+01", "significand": "4.506", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.567e-03", "significand": "5.567", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Amount concentration (1)", "number": "5.35e-02", "significand": "5.35", "exponent": "-2", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": []}]}]}}