Compilation - Nitroethane with 1-Decanol (IUPAC SDS Volume 77)
SDS Volume (4971)
Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None
Original Measurements
Francis, A. W.; J. Phys. Chem. 60, 20-7 (1956).
Variables:
Room Temp: 273 - 292 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The observations were made after vigorously shaking on glass stoppered graduated tubes of about 15 mL capacity immersed in water baths in large Dewar flasks. The water was agitated with a rapid stream of air bubbles. The temperature was adjusted by adding small amounts of cooler or warmer water occasionally as required.
Source and Purity of Materials:
- Eastman Kodak Co., distilled with 30 cm column with reflux; BP = 114-115°C; $n_{D}^{20}$ = 1.3920, $\rho^{20} = \pu{1046.9 g L-1}$.
- Source not specified; purified by crystallization; MP = 6.8°C; $n_{D}^{20}$ = 1.4372, $\rho^{20} = \pu{831.8 g L-1}$.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Components:
- Nitroethane, $\ce{ C2H5NO2 }$; [79-24-3] NIST WebBook
- 1-Decanol, $\ce{ C10H22O }$; [112-30-1] NIST WebBook
Experimental Data
Mutual solubility of nitroethane (1) and 1-decanol (2)
| $T$ (°C) | $T$ ($\pu{K}$) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 0.0 | 273.2 | 90.0 | 0.950 |
| 6.0 | 279.2 | 84.0 | 0.917 |
| 10.0 | 283.2 | 80.0 | 0.894 |
| 18.4 | 291.6 | 53.0 | UCST |
