{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4971/jsonld#"}], "@id": "", "generatedAt": "08-18-26 08:17:12", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4971/jsonld#", "@type": "sdo:scidataFramework", "uid": "77_64", "title": "Solubility data from IUPAC SDS Volume 77 (page ?) - Nitroethane with 1-Decanol", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Valerii P. Sazonov", "role": "compiler"}, {"@id": "author/2/", "@type": "dc:creator", "name": "Nikolai I. Lisov", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:scidataFramework", "sdo:scientificData", "sdo:stringvalue", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "obo:NCIT_C25206", "qudt:K", "sdo:numericvalue", "sdo:stringvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float", "xsd:str"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The observations were made after vigorously shaking on glass stoppered graduated tubes of about 15 mL capacity immersed in water baths in large Dewar flasks. The water was agitated with a rapid stream of air bubbles. The temperature was adjusted by adding small amounts of cooler or warmer water occasionally as required.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Nitroethane", "formula": "C2H5NO2", "casrn": "79-24-3", "iupacname": "1-nitroethane", "inchikey": "MCSAJNNLRCFZED-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "1-Decanol", "formula": "C10H22O", "casrn": "112-30-1", "iupacname": "decan-1-ol", "inchikey": "MWKFXSUHUHTGQN-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Nitroethane", "description": "Eastman Kodak Co., distilled with 30 cm column with reflux; BP = 114-115°C; $n_{D}^{20}$ = 1.3920, $\\rho^{20} = \\pu{1046.9 g L-1}$.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "1-Decanol", "description": "Source not specified; purified by crystallization; MP = 6.8°C; $n_{D}^{20}$ = 1.4372, $\\rho^{20} = \\pu{831.8 g L-1}$.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Nitroethane with 1-Decanol", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Kelvin", "unit#": "qudt:K"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.732e+02", "significand": 2.732, "exponent": 2, "sigfigs": 4}, {"@id": "condition/2/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.792e+02", "significand": 2.792, "exponent": 2, "sigfigs": 4}, {"@id": "condition/3/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.832e+02", "significand": 2.832, "exponent": 2, "sigfigs": 4}, {"@id": "condition/4/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.916e+02", "significand": 2.916, "exponent": 2, "sigfigs": 4}, {"@id": "condition/5/", "@type": "sdo:condition", "quantity#": "quantity/2/", "number": "2.732e+02", "significand": 2.732, "exponent": 2, "sigfigs": 4}, {"@id": "condition/6/", "@type": "sdo:condition", "quantity#": "quantity/2/", "number": "2.792e+02", "significand": 2.792, "exponent": 2, "sigfigs": 4}, {"@id": "condition/7/", "@type": "sdo:condition", "quantity#": "quantity/2/", "number": "2.832e+02", "significand": 2.832, "exponent": 2, "sigfigs": 4}, {"@id": "condition/8/", "@type": "sdo:condition", "quantity#": "quantity/2/", "number": "2.916e+02", "significand": 2.916, "exponent": 2, "sigfigs": 4}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/", "datapoint/4/"]}, {"@id": "datagroup/2/", "@type": "sdo:datagroup", "label": "Datagroup 2", "mixture#": "mixture/1/", "datapoints": ["datapoint/5/", "datapoint/6/", "datapoint/7/", "datapoint/8/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "77:064:001:002:001", "conditions#": ["condition/5/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.00e+01", "significand": 9.0, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.50e-01", "significand": 9.5, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "77:064:001:002:002", "conditions#": ["condition/6/"], "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.40e+01", "significand": 8.4, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.17e-01", "significand": 9.17, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "77:064:001:002:003", "conditions#": ["condition/7/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.00e+01", "significand": 8.0, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.94e-01", "significand": 8.94, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/4/", "@type": "sdo:datapoint", "uid": "77:064:001:002:004", "conditions#": ["condition/8/"], "data": [{"@id": "datapoint/4/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.30e+01", "significand": 5.3, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/4/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/4/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "UCST"}}]}, {"@id": "datapoint/5/", "@type": "sdo:datapoint", "uid": "77:064:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/5/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/5/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/5/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/6/", "@type": "sdo:datapoint", "uid": "77:064:001:001:002", "conditions#": ["condition/2/"], "data": [{"@id": "datapoint/6/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/6/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.90e+01", "significand": 1.9, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/6/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/6/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.31e-01", "significand": 3.31, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/7/", "@type": "sdo:datapoint", "uid": "77:064:001:001:003", "conditions#": ["condition/3/"], "data": [{"@id": "datapoint/7/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/7/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.10e+01", "significand": 2.1, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/7/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/7/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.59e-01", "significand": 3.59, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/8/", "@type": "sdo:datapoint", "uid": "77:064:001:001:004", "conditions#": ["condition/4/"], "data": [{"@id": "datapoint/8/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/8/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.30e+01", "significand": 5.3, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/8/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/8/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.04e-01", "significand": 7.04, "exponent": -1, "sigfigs": 3}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Francis, A. W.; J. Phys. Chem. 60, 20-7 (1956).", "doi": "10.1021/j150535a007", "url": "https://doi.org/10.1021/j150535a007"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 77 (page ?) - Nitroethane with 1-Decanol", "url": "https://doi.org/10.1063/1.1417522"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}