NIST-IUPAC Solubility Data Series

Nitromethane with Methyl esters unsaturated fatty acids (IUPAC SDS Volume 71)

SDS Volume

Volume 71. Nitromethane with Water or Organic Solvents, p None

Source Publication

Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Microchem. J. 7, 287-96 (1963).

Conditions:

Room Temp: 292 - 362 $\pu{K}$

Compiler:

V.P. Sazonov

Methodology:

The synthetic method was used. A Reichert microscope, type RCH, with a heating stage was used. A 26 x 38 mm slide was adapted to hold capillaries on the stage. Two glass strips were glued, using water glass, to the slide, leaving a 0.5 mm channel. The slide was then placed in the adjustable device of the heating stage. (1) and (2) were put into capillary tubing (0.2-0.3 mm diameter) by dipping consecutively into both liquids. The height of the liquid was 7-10 mm. Room temperature solids were melted on a glass slide over a microburner. The capillary was sealed at both ends to a length of 30-35 mm, then inserted into the channel on the slide and heated on the stage. The UCST was determined by following the appearance and disappearance of the meniscus.

Sample Information:

Fisher Scientific Co.; certified, No. N-98; $n_{D}^{20}$ = 1.3820, $\rho^{20} = \pu{1134 g L-1}$.
Obtained from the Hormel Foundation; purified by gas-liquid partition and thin-layer adsorption chromatography.