{"compilation": {"title": "Solubility data from IUPAC SDS Volume 71 (page ?) - Nitromethane with Methyl esters unsaturated fatty acids", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Microchem. J. 7, 287-96 (1963).", "pubtype": "paper", "url": "https://doi.org/10.1016/0026-265x(63)90053-5"}], "system": "Nitromethane with Methyl esters unsaturated fatty acids", "substances": [{"constituent": 1, "name": "Nitromethane", "formula": "CH3NO2 ", "molweight": 61.04, "casrn": "75-52-5", "inchi": "InChI=1S/CH3NO2/c1-2(3)4/h1H3", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N", "sample": "Fisher Scientific Co.; certified, No. N-98; $n_{D}^{20}$ = 1.3820, $\\rho^{20} = \\pu{1134 g L-1}$."}, {"constituent": 2, "name": "Methyl cis-9-octadecenoate", "formula": "C19H36O2", "molweight": 296.488, "casrn": "112-62-9", "inchi": "InChI=1S/C19H36O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(20)21-2/h10-11H,3-9,12-18H2,1-2H3/b11-10-", "inchikey": "QYDYPVFESGNLHU-KHPPLWFESA-N", "sample": "Obtained from the Hormel Foundation; purified by gas-liquid partition and thin-layer adsorption chromatography."}, {"constituent": 2, "name": "Methyl palmitelaidate", "formula": "C17H32O2", "molweight": 296.488, "casrn": "10030-74-7", "inchi": "InChI=1S/C17H32O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17(18)19-2/h8-9H,3-7,10-16H2,1-2H3/b9-8+", "inchikey": "IZFGRAGOVZCUFB-CMDGGOBGSA-N", "sample": "Obtained from the Hormel Foundation; purified by gas-liquid partition and thin-layer adsorption chromatography."}, {"constituent": 2, "name": "Methyl cis-11-octadecenoate", "formula": "C17H32O2", "molweight": 296.488, "casrn": "1937-63-9", "inchi": "InChI=1S/C19H36O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(20)21-2/h8-9H,3-7,10-18H2,1-2H3/b9-8-", "inchikey": "PVVODBCDJBGMJL-HJWRWDBZSA-N", "sample": "Obtained from the Hormel Foundation; purified by gas-liquid partition and thin-layer adsorption chromatography."}, {"constituent": 2, "name": "Methyl (Z)-octadec-12-enoate", "formula": "C19H36O2", "molweight": 296.5, "casrn": "2733-86-0", "inchi": "InChI=1S/C19H36O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(20)21-2/h7-8H,3-6,9-18H2,1-2H3/b8-7-", "inchikey": "LMWAESDDOGRMOK-FPLPWBNLSA-N", "sample": "Obtained from the Hormel Foundation; purified by gas-liquid partition and thin-layer adsorption chromatography."}, {"constituent": 2, "name": "Methyl cis-6-octadecenoate", "formula": "C19H36O2", "molweight": 296.5, "casrn": "2777-58-4", "inchi": "InChI=1S/C19H36O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(20)21-2/h13-14H,3-12,15-18H2,1-2H3/b14-13-", "inchikey": "QRTVDKVXAFJVRU-YPKPFQOOSA-N", "sample": "Obtained from the Hormel Foundation; purified by gas-liquid partition and thin-layer adsorption chromatography."}, {"constituent": 2, "name": "Methyl octadec-9-enoate", "formula": "C19H36O2", "molweight": 296.5, "casrn": "1937-62-8", "inchi": "InChI=1S/C19H36O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(20)21-2/h10-11H,3-9,12-18H2,1-2H3", "inchikey": "QYDYPVFESGNLHU-UHFFFAOYSA-N", "sample": "Obtained from the Hormel Foundation; purified by gas-liquid partition and thin-layer adsorption chromatography."}, {"constituent": 2, "name": "Methyl cis-11-eicosenoate", "formula": "C21H40O2", "molweight": 324.5, "casrn": "2390-09-2", "inchi": "InChI=1S/C21H40O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20-21(22)23-2/h10-11H,3-9,12-20H2,1-2H3/b11-10-", "inchikey": "RBKMRGOHCLRTLZ-KHPPLWFESA-N", "sample": "Obtained from the Hormel Foundation; purified by gas-liquid partition and thin-layer adsorption chromatography."}, {"constituent": 2, "name": "Methyl (Z)-docos-13-enoate", "formula": "C23H44O2", "molweight": 352.6, "casrn": "1120-34-9", "inchi": "InChI=1S/C23H44O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20-21-22-23(24)25-2/h10-11H,3-9,12-22H2,1-2H3/b11-10-", "inchikey": "ZYNDJIBBPLNPOW-KHPPLWFESA-N", "sample": "Obtained from the Hormel Foundation; purified by gas-liquid partition and thin-layer adsorption chromatography."}, {"constituent": 2, "name": "Methyl (Z)-tetracos-15-enoate", "formula": "C25H48O2", "molweight": 380.6, "casrn": "2733-88-2", "inchi": "InChI=1S/C25H48O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20-21-22-23-24-25(26)27-2/h10-11H,3-9,12-24H2,1-2H3/b11-10-", "inchikey": "AINIZSBLAFHZCP-KHPPLWFESA-N", "sample": "Obtained from the Hormel Foundation; purified by gas-liquid partition and thin-layer adsorption chromatography."}], "method": "The synthetic method was used. A Reichert microscope, type RCH, with a heating stage was used. A 26 x 38 mm slide was adapted to hold capillaries on the stage. Two glass strips were glued, using water glass, to the slide, leaving a 0.5 mm channel. The slide was then placed in the adjustable device of the heating stage. (1) and (2) were put into capillary tubing (0.2-0.3 mm diameter) by dipping consecutively into both liquids. The height of the liquid was 7-10 mm. Room temperature solids were melted on a glass slide over a microburner. The capillary was sealed at both ends to a length of 30-35 mm, then inserted into the channel on the slide and heated on the stage. The UCST was determined by following the appearance and disappearance of the meniscus.", "dataset": [{"series": 1, "title": "Upper critical solution temperatures of the systems nitromethane + methyl ester unsaturated fatty acid", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.90e+01", "significand": "1.90", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.922e+02", "significand": "2.922", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "4.10e+01", "significand": "4.10", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.142e+02", "significand": "3.142", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "4.10e+01", "significand": "4.10", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.142e+02", "significand": "3.142", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "4.10e+01", "significand": "4.10", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.142e+02", "significand": "3.142", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "4.10e+01", "significand": "4.10", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.142e+02", "significand": "3.142", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "4.60e+01", "significand": "4.60", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.192e+02", "significand": "3.192", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "5.85e+01", "significand": "5.85", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.317e+02", "significand": "3.317", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "7.50e+01", "significand": "7.50", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.482e+02", "significand": "3.482", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}, {"pntnum": 9, "conditions": [{"property": "Ambient temperature", "number": "8.85e+01", "significand": "8.85", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.617e+02", "significand": "3.617", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}]}]}}