Compilation - Argon with Nitrogen, Carbon dioxide, Methane, Ethane and Poly(trimethylsilyl propyne) (PTMSP) (IUPAC SDS Volume 70)
SDS Volume (4121)
Volume 70. Solubility of Gases in Glassy Polymers, p None
Original Measurements
Bondar, V. I.; Kukharskii, Yu. M.; Volkov, V. V.; Abstracts, 5th Int. Symposium on Solubility Phenomena, Moscow, p. 227 (1992).
Variables:
Room Temp:
298
$\pu{K}$
Pressure:
0 - 11
$\pu{MPa}$
Prepared by:
Method/Apparatus/Procedure:
Solubility was measured by means of gravimetric method using Sartorius 4436 microbalance.
Source and Purity of Materials:
- PTMSP: prepared according the method of Maeuda et al. [1].
Estimated Errors:
Ambient temperature: No information gives.
References
1 Masuda, T.; Isobe, E.; Higashimura, T.; Takada, K.; J. Am. Chem. Soc. 1983, 105, 7473.
Components:
- Argon, $\ce{ Ar }$; [7440-37-1] NIST WebBook
- Nitrogen (Molecule), $\ce{ N2 }$; [7727-37-9] NIST WebBook
- Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
- Methane, $\ce{ CH4 }$; [74-82-8] NIST WebBook
- Ethane, $\ce{ C2H6 }$; [74-84-0] NIST WebBook
- Poly(trimethylsilyl propyne) (PTMSP), $\ce{ (C7H16Si)n }$; [87842-32-8] NIST WebBook
Experimental Data
Dual mode sorption parameters for various gases in PTMSP at 298 K
| $k_{\rm{D}}$ ($\pu{cm3(g) cm-3(s) atm-1}$) | $C_{\rm{H}}^{\prime}$ ($\pu{cm3/cm3}$) | $b$ ($\pu{atm-1}$) |
|---|---|---|
| 0.096 | 90.9 | 0.015 |
| 0.062 | 60.0 | 0.017 |
| 1.300 | 139.0 | 0.064 |
| 0.200 | 88.3 | 0.041 |
| 2.830 | 75.1 | 0.473 |
None
