{"compilation": {"title": "Solubility data from IUPAC SDS Volume 70 (page ?) - Argon, Nitrogen, Carbon dioxide, Methane, Ethane and Poly(trimethylsilyl propyne) (PTMSP)", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii I. Bondar", "sources": [{"citation": "Bondar, V. I.; Kukharskii, Yu. M.; Volkov, V. V.; Abstracts, 5th Int. Symposium on Solubility Phenomena, Moscow, p. 227 (1992).", "pubtype": "symposium"}], "system": "Argon, Nitrogen, Carbon dioxide, Methane, Ethane and Poly(trimethylsilyl propyne) (PTMSP)", "substances": [{"constituent": 2, "name": "Poly(trimethylsilyl propyne) (PTMSP)", "formula": "(C7H16Si)n", "molweight": 128.29, "casrn": "87842-32-8", "inchi": "InChI=1S/C7H16Si/c1-6-7(2)8(3,4)5/h6H,1-5H3/b7-6-", "inchikey": "QOZLCBPYZLFNST-SREVYHEPSA-N", "sample": "PTMSP: prepared according the method of Maeuda et al. [1]."}, {"constituent": 1, "name": "Argon", "formula": "Ar", "molweight": 39.948, "casrn": "7440-37-1", "inchi": "InChI=1S/Ar", "inchikey": "XKRFYHLGVUSROY-UHFFFAOYSA-N"}, {"constituent": 1, "name": "Nitrogen (Molecule)", "formula": "N2", "molweight": 28.0134, "casrn": "7727-37-9", "inchi": "InChI=1S/N2/c1-2", "inchikey": "IJGRMHOSHXDMSA-UHFFFAOYSA-N"}, {"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N"}, {"constituent": 1, "name": "Methane", "formula": "CH4", "molweight": 16.0425, "casrn": "74-82-8", "inchi": "InChI=1S/CH4/h1H4", "inchikey": "VNWKTOKETHGBQD-UHFFFAOYSA-N"}, {"constituent": 1, "name": "Ethane", "formula": "C2H6", "molweight": 30.069, "casrn": "74-84-0", "inchi": "InChI=1S/C2H6/c1-2/h1-2H3", "inchikey": "OTMSDBZUPAUEDD-UHFFFAOYSA-N"}], "method": "Solubility was measured by means of gravimetric method using Sartorius 4436 microbalance.", "reference": {"citation": "Masuda, T.; Isobe, E.; Higashimura, T.; Takada, K.; J. Am. Chem. Soc. 1983, 105, 7473.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja00363a061"}, "dataset": [{"series": 1, "title": "Dual mode sorption parameters for various gases in PTMSP at 298 K", "points": [{"pntnum": 1, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "9.6e-02", "significand": "9.6", "exponent": "-2", "sigfigs": "2", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "9.09e+01", "significand": "9.09", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.5e-02", "significand": "1.5", "exponent": "-2", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "6.2e-02", "significand": "6.2", "exponent": "-2", "sigfigs": "2", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "6.00e+01", "significand": "6.00", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.7e-02", "significand": "1.7", "exponent": "-2", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "1.300e+00", "significand": "1.300", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "1.390e+02", "significand": "1.390", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "6.4e-02", "significand": "6.4", "exponent": "-2", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "2.00e-01", "significand": "2.00", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "8.83e+01", "significand": "8.83", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "4.1e-02", "significand": "4.1", "exponent": "-2", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "2.830e+00", "significand": "2.830", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "7.51e+01", "significand": "7.51", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "4.73e-01", "significand": "4.73", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}]}]}}