SDS Volume (3777)

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Original Measurements

Bonner, W. D.; J. Phys. Chem. 14, 738 (1909).

Variables:

Room Temp: 273 $\pu{K}$

Prepared by:

A. Skrzecz

Method/Apparatus/Procedure:

In a tube 1 cm diameter and 12 cm long known amount, by weight, of hydrocarbon and water were placed into a temperature controlled bath. The contents of the tube were stirred and alcohol was added gradually until a homogeneous solution was obtained. Observations were made visually through the telescope of a cathetometer. The samples were always weighed immediately before and after each experiment. Concentrations were reported as weight of water in 1 g of binary water-hydrocarbon mixture and the weight of alcohol necessary to make a homogenous solution. The mass of binary water-hydrocarbon mixture was about 1 g; the mass of alcohol-up to 5 g.

Source and Purity of Materials:
  1. Kahlbaum; presumably dried and distilled; $n^{14}$ = 1.3370.
  2. Kahlbaum; presumably dried and distilled; $n^{14}$ = 1.38382.
  3. Source not specified.
Estimated Errors:

Ambient temperature: Accuracy of weighing 0.001 g.
Mass concentration (m/v) (1): Not reported.

Components:
  1. Methanol, $\ce{ CH4O }$; [67-56-1] NIST WebBook
  2. Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Compositions along the saturation curve
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
0.0273.2 0.81060.17670.90180.0731
0.0273.2 0.83580.13790.89500.0549
0.0273.2 0.85100.10300.87620.0394
0.0273.2 0.86190.08090.86740.0303
0.0273.2 0.86420.06670.85400.0245
0.0273.2 0.86190.04810.82880.0172
0.0273.2 0.86150.04570.82560.0163
0.0273.2 0.84590.03080.78570.0106
0.0273.2 0.83370.02830.76509.6 x 10-3
0.0273.2 0.79640.01930.70406.4 x 10-3
0.0273.2 0.63755.8 x 10-30.50041.7 x 10-3

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