SDS Volume (3656)

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Original Measurements

Bonner, W. D.; J. Phys. Chem. 14, 738 (1909).

Variables:

Room Temp: 273 $\pu{K}$

Prepared by:

A. Skrzecz

Method/Apparatus/Procedure:

In a tube 1 cm diameter and 12 cm long known amount, by weight, of hydrocarbon and water were placed into a temperature controlled bath. The contents of the tube were stirred and alcohol was added gradually until a homogeneous solution was obtained. Observations were made visually through the telescope of a cathetometer. The samples were always weighed immediately before and after each experiment. Concentrations were reported as weight of water in 1 g of binary water-hydrocarbon mixture and the weight of alcohol necessary to make a homogenous solution. The mass of binary water-hydrocarbon mixture was about 1 g; the mass of alcohol-up to 5 g.

Source and Purity of Materials:
  1. Kahlbaum; presumably dried and distilled.
  2. Kahlbaum; presumably dried and distilled.
  3. Source not specified.
Estimated Errors:

Ambient temperature: Accuracy of weighing 0.0001 g.
Mass concentration (m/v) (1): Not reported.

Components:
  1. Ethanol, $\ce{ C2H6O }$; [64-17-5] NIST WebBook
  2. 1,4-Dimethylbenzene, $\ce{ C8H10 }$; [106-42-3] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Compositions along the saturation curve
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
15.0288.2 0.23430.73970.37680.5161
15.0288.2 0.34680.60480.47320.3581
15.0288.2 0.36310.58600.48560.3401
15.0288.2 0.43180.49940.52380.2629
15.0288.2 0.52200.37220.55320.1734
15.0288.2 0.56710.30910.55720.1318
15.0288.2 0.63370.17440.52800.0630
15.0288.2 0.64070.13580.50400.0464
15.0288.2 0.63540.10860.47530.0353
15.0288.2 0.61900.07350.43080.0222
15.0288.2 0.57410.03750.36250.0103

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