Compilation - 1-Chloropentane with Water (IUPAC SDS Volume 68)
SDS Volume (3497)
Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None
Original Measurements
Hutchinson, C. A.; Lyon, A. M.; Columbia University Report A-745, July 1, 1943.
Variables:
Room Temp: 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A 1 to 15 volume ratio mixture of water and 1-chloropentane was introduced into an equilibration flask and then lowered into the waterbath thermostat. The assembly was shaken mechanically for about 90 minutes at a constant temperature. The amount of water in the organic phase was determined by a modified Karl Fischer titration. The determination was done in triplicate. The description of procedure was taken from a secondary source [1]. The original university report is no longer available.
Source and Purity of Materials:
- Distilled.
- Source not given. Purified and dried before use.
Estimated Errors:
Ambient temperature: ±0.05 K.
Mass concentration (m/v) (1): ±2.5%.
References
1 Eidinoff, M. L.; Joris, G. G.; Taylor, H. S.; Urey, H. C.; eds., Production of Heavy Water (McGraw_Hill, New York, 1955), p. 129.
Components:
- 1-Chloropentane, $\ce{ C5H11Cl }$; [543-59-9] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $mol_{1}/\pu{100 g}$ (mol/g) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 25 | 2.53 x 10-3 | 0.0456 | 2.69 x 10-3 |
