{"compilation": {"title": "Solubility data from IUPAC SDS Volume 68 (page ?) - 1-Chloropentane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Hutchinson, C. A.; Lyon, A. M.; Columbia University Report A-745, July 1, 1943.", "pubtype": "report"}], "system": "1-Chloropentane with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Source not given. Purified and dried before use."}, {"constituent": 1, "name": "1-Chloropentane", "formula": "C5H11Cl", "molweight": 106.594, "casrn": "543-59-9", "inchi": "InChI=1S/C5H11Cl/c1-2-3-4-5-6/h2-5H2,1H3", "inchikey": "SQCZQTSHSZLZIQ-UHFFFAOYSA-N", "sample": "Distilled."}], "method": "A 1 to 15 volume ratio mixture of water and 1-chloropentane was introduced into an equilibration flask and then lowered into the waterbath thermostat. The assembly was shaken mechanically for about 90 minutes at a constant temperature. The amount of water in the organic phase was determined by a modified Karl Fischer titration. The determination was done in triplicate. The description of procedure was taken from a secondary source [1]. The original university report is no longer available.", "reference": {"citation": "Eidinoff, M. L.; Joris, G. G.; Taylor, H. S.; Urey, H. C.; eds., Production of Heavy Water (McGraw_Hill, New York, 1955), p. 129.", "pubtype": "book"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole (1) per 100 gram", "number": "2.53e-03", "significand": "2.53", "exponent": "-3", "sigfigs": "3", "unit": "mol/g"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "4.56e-02", "significand": "4.56", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "2.69e-03", "significand": "2.69", "exponent": "-3", "sigfigs": "3", "unit": "1"}]}]}]}}