SDS Volume
Volume 67. Halogenated Ethanes and Ethenes with Water, p 458
Source Publication
Antropov, L. I.; Populyai, V. E.; Simonov, V. D.; Shamsutdinov, T. M.; Russ. J. Phys. Chem. 1972, 46, 311-2.
Conditions:
Room Temp: 288 - 299 $\pu{K}$
Compiler:
Methodology:
Alexejew's synthetic solubility method of solubility determination was used [1]. A fixed weight of trichloroethene and water was sealed in a tube and the mixture was subjected to gradually increasing temperature with constant agitation. The appearance of opalescence or clouding was the indication of the saturation temperature. The temperature was then allowed to fall and an observation made, while the tube was constantly agitated, of the temperature of the first appearance of opalescence.The observation was repeated several times.
Sample Information:
- Source and purity not given.
- Distilled.
Measurement Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): Not specified.
Methodology Citation
System Components:
- Trichloroethylene, $\ce{ C2HCl3 }$; [79-01-6] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | 100w2 | $x_{1}$ a | $x_{2}$ a |
|---|---|---|---|---|
| 15 | 0.101 | - | 1.39 x 10-4 | - |
| 18 | - | 0.021 | - | 1.53 x 10-3 |
| 20 | 0.109 | - | 1.50 x 10-4 | - |
| 22 | - | 0.024 | - | 1.75 x 10-3 |
| 26 | 0.122 | 0.032 | 1.67 x 10-4 | 2.33 x 10-3 |
