{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/3427/jsonld#"}], "@id": "", "generatedAt": "10-19-26 14:41:52", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/3427/jsonld#", "@type": "sdo:scidataFramework", "uid": "67_99", "title": "Solubility data from IUPAC SDS Volume 67 (page 458) - Trichloroethene with Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Ari L. Horvath", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:stringvalue", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "obo:NCIT_C25206", "qudt:DEG_C", "sdo:numericvalue", "sdo:stringvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float", "xsd:str"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "Alexejew's synthetic solubility method of solubility determination was used [1]. A fixed weight of trichloroethene and water was sealed in a tube and the mixture was subjected to gradually increasing temperature with constant agitation. The appearance of opalescence or clouding was the indication of the saturation temperature. The temperature was then allowed to fall and an observation made, while the tube was constantly agitated, of the temperature of the first appearance of opalescence.The observation was repeated several times.", "references": [{"@id": "procedure/1/reference/1/", "@type": "sdo:reference", "number": 1, "citation": "Alexejew, W.; Ann. Phys. Chem. 28, 305 (1886).", "doi": "10.1002/andp.18862640611", "url": "https://doi.org/10.1002/andp.18862640611"}]}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Trichloroethylene", "formula": "C2HCl3", "casrn": "79-01-6", "iupacname": "1,1,2-trichloroethene", "inchikey": "XSTXAVWGXDQKEL-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Trichloroethylene", "description": "Source and purity not given.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Water", "description": "Distilled.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Trichloroethene with Water", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Degree celsius", "unit#": "qudt:DEG_C"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "1.5e+01", "significand": 1.5, "exponent": 1, "sigfigs": 2}, {"@id": "condition/2/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "1.8e+01", "significand": 1.8, "exponent": 1, "sigfigs": 2}, {"@id": "condition/3/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.0e+01", "significand": 2.0, "exponent": 1, "sigfigs": 2}, {"@id": "condition/4/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.2e+01", "significand": 2.2, "exponent": 1, "sigfigs": 2}, {"@id": "condition/5/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.6e+01", "significand": 2.6, "exponent": 1, "sigfigs": 2}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/", "datapoint/4/", "datapoint/5/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "67:099:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.01e-01", "significand": 1.01, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.39e-04", "significand": 1.39, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/1/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/1/datum/4/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "67:099:001:001:002", "conditions#": ["condition/2/"], "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.1e-02", "significand": 2.1, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/2/datum/3/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/2/datum/3/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/2/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/2/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.53e-03", "significand": 1.53, "exponent": -3, "sigfigs": 3}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "67:099:001:001:003", "conditions#": ["condition/3/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.09e-01", "significand": 1.09, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/3/datum/3/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/3/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.50e-04", "significand": 1.5, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/3/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/3/datum/4/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/4/", "@type": "sdo:datapoint", "uid": "67:099:001:001:004", "conditions#": ["condition/4/"], "data": [{"@id": "datapoint/4/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/4/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/4/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.4e-02", "significand": 2.4, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/4/datum/3/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/4/datum/3/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/4/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/4/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.75e-03", "significand": 1.75, "exponent": -3, "sigfigs": 3}}]}, {"@id": "datapoint/5/", "@type": "sdo:datapoint", "uid": "67:099:001:001:005", "conditions#": ["condition/5/"], "data": [{"@id": "datapoint/5/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/5/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.22e-01", "significand": 1.22, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/5/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.2e-02", "significand": 3.2, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/5/datum/3/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/5/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.67e-04", "significand": 1.67, "exponent": -4, "sigfigs": 3}}, {"@id": "datapoint/5/datum/4/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/5/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.33e-03", "significand": 2.33, "exponent": -3, "sigfigs": 3}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Antropov, L. I.; Populyai, V. E.; Simonov, V. D.; Shamsutdinov, T. M.; Russ. J. Phys. Chem. 1972, 46, 311-2."}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 67 (page 458) - Trichloroethene with Water", "url": "https://doi.org/10.1063/1.556039"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}