Compilation - Water with 1,2-Dichloroethane (IUPAC SDS Volume 67)
SDS Volume (3307)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 595
Original Measurements
Sellers, P.; Acta Chem. Scand. 1971, 25, 2295.
Variables:
Room Temp: 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Samples of 1,2-dichloroethane saturated with water were analyzed by two different methods, a gas chromatographic method and a calcium hydride reaction method. The gas chromatographic method used a Varian Aerograph fitted with a thermal conductor and the column packed with Poropak P and Q. The calcium hydride reaction method consisted of mixing the sample with Ca$\ce{H2}$ and determining the amount of hydrogen evolved from the reaction between the hydride and water present in the samples.
Source and Purity of Materials:
- Distilled.
- British Drug House, dried on molecular sieves before use.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): See table above.
Components:
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
- 1,2-Dichloroethane, $\ce{ C2H4Cl2 }$; [107-06-2] NIST WebBook
Experimental Data
| $T$ (°C) | S1:2 | $x_{1}$ |
|---|---|---|
| 25 | 1.24 x 10-3 | 6.77 x 10-3 |
| 25 | 1.20 x 10-3 | 7.04 x 10-3 |
