Compilation - 1,1,2-Trichloroethane with Water (IUPAC SDS Volume 67)
SDS Volume (3209)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 548
Original Measurements
Barr, R. S.; Newsham, D. M. T.; Fluid Phase Equilib. 1987, 35, 189-205.
Variables:
Room Temp: 293 - 323 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The water-rich mixture was studied using gas-liquid chromatography in which a mixture of methane and 1,1,2-trichloroethane vapor passed through the sampling loop. The eluted 1,1,2-trichloroethane was determined with a flame ionization detector. The organic-rich mixture was studied using an isopiestic method in which $\ce{CaCl2}$ solution controlled the partial pressure of water. The water concentration of the organic phase was determined by using a Karl Fischer titration apparatus.
Source and Purity of Materials:
- Aldrich Chemical Co. Ltd., redistilled in a glass sieve tray column before use.
- Double distilled tap water.
Estimated Errors:
Ambient temperature: ±0.05 K.
Mass concentration (m/v) (1): Not specified.
Components:
- 1,1,2-Trichloroethane, $\ce{ C2H3Cl3 }$; [79-00-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Mole fraction of 1,1,2-trichloroethane (x1) was calculated from the activity coefficients at infinite dilution (γ∞1) using the relation x1 = 1/γ∞1.
| $T$ (°C) | $x_{1}$ | $x_{2}$ | $x_{2}$ | 100w1 | 100w2 |
|---|---|---|---|---|---|
| 20 | 6.67 x 10-4 | 8.11 x 10-3 | 8.11 x 10-3 | 0.492 | 1.10 x 10-3 |
| 35 | 6.58 x 10-4 | 0.0123 | 0.0123 | 0.485 | 1.68 x 10-3 |
| 50 | 6.99 x 10-4 | 0.0175 | 0.0175 | 0.515 | 2.40 x 10-3 |
