Compilation - Bromobenzene with Water (IUPAC SDS Volume 20)
SDS Volume (32)
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 147
Original Measurements
Nelson, H. D.; Smit, J. H.; S. Afr. Tydskr. Chem. 1978, 31(2), 76.
Variables:
Room Temp: 4 - 45.5 °C
Prepared by:
Method/Apparatus/Procedure:
Water was saturated through the vapor phase with bromobenzene in a special flask [1] using a shaker in a thermostat bath for 24 hours. A gas chromatographic analysis of the samples was done by injection into a 5% Apiezon M stainless steel column with Celite as the supporter. The column length was 1.5 m and the temp. was 120 °C. The chromatograph was equipped with a flame ionization detector. Three samples were analyzed from each flask.
Source and Purity of Materials:
- Not specified.
- not specified.
Estimated Errors:
Ambient temperature: ±0.1 K (compiler).
Mass concentration (m/v) (1): ±14.9% (compiler).
References
1 Nelson, H. D.; De Ligny, C. L.; Recl. Trav. Chim. Pays-Bas 1968, 87, 528-44.
Components:
- Bromobenzene, $\ce{ C6H5Br }$; [108-86-1] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | MR1 (g/kg) | m1 (mol/kg) |
|---|---|---|---|
| 5 | 1.34 x 10-5 | 0.1168 | 7.438 x 10-4 |
| 25 | 1.7 x 10-5 | 0.148 | 9.44 x 10-4 |
| 39 | 2.8 x 10-5 | 0.244 | 1.55 x 10-3 |
| 45.5 | 3.6 x 10-5 | 0.314 | 2.00 x 10-3 |
(a) Calculated by the compiler.
(b) Calculated by F. W. Getzen.
(c) Reported.
