{"compilation": {"title": "Solubility data from IUPAC SDS Volume 20 (page 147) - Bromobenzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Nelson, H. D.; Smit, J. H.; S. Afr. Tydskr. Chem. 1978, 31(2), 76.", "pubtype": "paper"}], "system": "Bromobenzene with Water", "substances": [{"constituent": 1, "name": "Bromobenzene", "formula": "C6H5Br", "molweight": 157.008, "casrn": "108-86-1", "inchi": "InChI=1S/C6H5Br/c7-6-4-2-1-3-5-6/h1-5H", "inchikey": "QARVLSVVCXYDNA-UHFFFAOYSA-N", "sample": "Not specified."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "not specified."}], "method": "Water was saturated through the vapor phase with bromobenzene in a special flask [1] using a shaker in a thermostat bath for 24 hours. A gas chromatographic analysis of the samples was done by injection into a 5% Apiezon M stainless steel column with Celite as the supporter. The column length was 1.5 m and the temp. was 120 \u00b0C. The chromatograph was equipped with a flame ionization detector. Three samples were analyzed from each flask.", "reference": {"citation": "Nelson, H. D.; De Ligny, C. L.; Recl. Trav. Chim. Pays-Bas 1968, 87, 528-44.", "pubtype": "paper", "url": "https://doi.org/10.1002/recl.19680870505"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "5e+00", "significand": "5", "exponent": "0", "sigfigs": "1", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.34e-05", "significand": "1.34", "exponent": "-5", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.168e-01", "significand": "1.168", "exponent": "-1", "sigfigs": "4", "unit": "g/kg"}, {"property": "Molality (1 in 2)", "number": "7.438e-04", "significand": "7.438", "exponent": "-4", "sigfigs": "4", "unit": "mol/kg"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.7e-05", "significand": "1.7", "exponent": "-5", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.48e-01", "significand": "1.48", "exponent": "-1", "sigfigs": "3", "unit": "g/kg"}, {"property": "Molality (1 in 2)", "number": "9.44e-04", "significand": "9.44", "exponent": "-4", "sigfigs": "3", "unit": "mol/kg"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.9e+01", "significand": "3.9", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.8e-05", "significand": "2.8", "exponent": "-5", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "2.44e-01", "significand": "2.44", "exponent": "-1", "sigfigs": "3", "unit": "g/kg"}, {"property": "Molality (1 in 2)", "number": "1.55e-03", "significand": "1.55", "exponent": "-3", "sigfigs": "3", "unit": "mol/kg"}], "supplemental": []}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "4.55e+01", "significand": "4.55", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "3.6e-05", "significand": "3.6", "exponent": "-5", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "3.14e-01", "significand": "3.14", "exponent": "-1", "sigfigs": "3", "unit": "g/kg"}, {"property": "Molality (1 in 2)", "number": "2.00e-03", "significand": "2.00", "exponent": "-3", "sigfigs": "3", "unit": "mol/kg"}], "supplemental": []}]}]}}