SDS Volume
Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None
Source Publication
Vázquez, G.; Chenlo, F.; Pereira, G.; Peaguda, J.; An. Quim. 1994, 90, 324-28.
Conditions:
Room Temp:
298.1
$\pu{K}$
Pressure:
1.013 bar
$\pu{bar}$
Molality (2):
m2/mol kg-1 = 0.245 - 1.835
mol/kg
Compiler:
Methodology:
The apparatus is a combination of previous designs [1,2]. It was modified to achieve a more accurate determination of the volume of the absorbent liquid. The apparatus measures the volume of absorbed gas as the volume of mercury that must be supplied to the system in order to restore the initial pressure.
The raw solubility data obtained are gas/ liquid volume ratios. A detailed description of apparatus, method and procedure is given in [3].
Sample Information:
- Commercial, purity 99.5 mole%
- Merck. Grade not given.
- Distilled and degassed.
Measurement Errors:
Ambient temperature: δT/K = ±0.1
Mass concentration (m/v) (1): δc1/c1 < ±1% [estimated by compiler on the basis of the information in Ref. 3]
Pressure: δP/bar = ±0.001
Methodology Citations
1
Alvarez, J. R.; Fernandez, A.; Coll, A., Ing. Quim. 1984, 16, 67.
2
Haimour, N.M.; J. Chem. Eng. Data 1990, 35, 177.
3
Vázquez, G.; Chenlo, F.; Pereira, G.; Peaguda, J.; J. Chem. Eng. Data 1994, 39, 639.
System Components:
- Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
- Potassium iodide, $\ce{ KI }$; [7681-11-0] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | m2 (mol/kg) | $L$ | $\rho, (20^{\circ}C)$ (g/L) | $C_{1}$ (mol/dm3) | Cm1 (g/dm3) |
|---|---|---|---|---|---|
| 298.1 | 0.245c | 0.741e | 1.024 x 103b | 0.0303d | 4E+1a |
| 298.1 | 0.495c | 0.714e | 1.053 x 103b | 0.0292d | 8E+1a |
| 298.1 | 0.751c | 0.692e | 1.082 x 103b | 0.0283d | 1.2E+2a |
| 298.1 | 1.014c | 0.692e | 1.111 x 103b | 0.0283d | 1.6E+2a |
| 298.1 | 1.280c | 0.665e | 1.141 x 103b | 0.0272d | 2E+2a |
| 298.1 | 1.563c | 0.658e | 1.165 x 103b | 0.0269d | 2.4E+2a |
| 298.1 | 1.835c | 0.653e | 1.199 x 103b | 0.0267d | 2.8E+2a |
(a) γ2 = mass concentration of KI
(b) p = density of aqueous KI solution
(c) m2 = molality of KI; calculated by the compiler.
(d) c1 = solubility of CO2
(e) L = Ostwald coefficient [cm3 cm-3]


