{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/2730/jsonld#"}], "@id": "", "generatedAt": "10-19-26 15:07:22", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/2730/jsonld#", "@type": "sdo:scidataFramework", "uid": "62_241", "title": "Solubility data from IUPAC SDS Volume 62 (page ?) - Carbon dioxide with Potassium iodide and Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Pirketta Scharlin", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afq:AFQ_0000168", "afrl:0000269", "afrl:0000270", "obo:NCIT_C179798", "obo:NCIT_C25206", "obo:NCIT_C75762", "qudt:K", "sdo:numericvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The apparatus is a combination of previous designs [1,2]. It was modified to achieve a more accurate determination of the volume of the absorbent liquid. The apparatus measures the volume of absorbed gas as the volume of mercury that must be supplied to the system in order to restore the initial pressure.<br/>The raw solubility data obtained are gas/ liquid volume ratios. A detailed description of apparatus, method and procedure is given in [3].", "references": [{"@id": "procedure/1/reference/1/", "@type": "sdo:reference", "number": 1, "citation": "Alvarez, J. R.; Fernandez, A.; Coll, A., Ing. Quim. 1984, 16, 67."}, {"@id": "procedure/1/reference/2/", "@type": "sdo:reference", "number": 1, "citation": "Haimour, N.M.; J. Chem. Eng. Data 1990, 35, 177.", "doi": "10.1021/je00060a024", "url": "https://doi.org/10.1021/je00060a024"}, {"@id": "procedure/1/reference/3/", "@type": "sdo:reference", "number": 1, "citation": "V\u00e1zquez, G.; Chenlo, F.; Pereira, G.; Peaguda, J.; J. Chem. Eng. Data 1994, 39, 639.", "doi": "10.1021/je00016a002", "url": "https://doi.org/10.1021/je00016a002"}]}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Carbon dioxide", "formula": "CO2", "casrn": "124-38-9", "iupacname": "carbon dioxide", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Potassium iodide", "formula": "KI", "casrn": "7681-11-0", "iupacname": "potassium iodide", "inchikey": "NLKNQRATVPKPDG-UHFFFAOYSA-M"}, {"@id": "substance/3/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Carbon dioxide", "description": "Commercial, purity 99.5 mole%", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Potassium iodide", "description": "Merck. Grade not given.", "substance#": "substance/2/"}, {"@id": "chemical/3/", "@type": "sdo:chemical", "name": "Water", "description": "Distilled and degassed.", "substance#": "substance/3/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Carbon dioxide with Potassium iodide and Water", "type": "ternary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/3/", "@type": "sdo:constituent", "chemical": "chemical 3", "chemical#": "chemical/3/", "role": "solvent", "role#": "afrl:0000269"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Kelvin", "unit#": "qudt:K"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.981e+02", "significand": 2.981, "exponent": 2, "sigfigs": 4}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/", "datapoint/4/", "datapoint/5/", "datapoint/6/", "datapoint/7/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "62:241:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.45e-01", "significand": 2.45, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Ostwald coefficient", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.41e-01", "significand": 7.41, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Mass density", "quantity#": "obo:NCIT_C75762", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.024e+03", "significand": 1.024, "exponent": 3, "sigfigs": 4}}, {"@id": "datapoint/1/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/1/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.03e-02", "significand": 3.03, "exponent": -2, "sigfigs": 3}}, {"@id": "datapoint/1/datum/5/", "@type": "sdo:datum", "quantity": "Mass concentration (m/v) (1)", "quantity#": "obo:NCIT_C179798", "value": {"@id": "datapoint/1/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4e+01", "significand": 4.0, "exponent": 1, "sigfigs": 1}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "62:241:001:001:002", "conditions#": ["condition/2/"], "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.95e-01", "significand": 4.95, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Ostwald coefficient", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.14e-01", "significand": 7.14, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/2/datum/3/", "@type": "sdo:datum", "quantity": "Mass density", "quantity#": "obo:NCIT_C75762", "value": {"@id": "datapoint/2/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.053e+03", "significand": 1.053, "exponent": 3, "sigfigs": 4}}, {"@id": "datapoint/2/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/2/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.92e-02", "significand": 2.92, "exponent": -2, "sigfigs": 3}}, {"@id": "datapoint/2/datum/5/", "@type": "sdo:datum", "quantity": "Mass concentration (m/v) (1)", "quantity#": "obo:NCIT_C179798", "value": {"@id": "datapoint/2/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8e+01", "significand": 8.0, "exponent": 1, "sigfigs": 1}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "62:241:001:001:003", "conditions#": ["condition/3/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.51e-01", "significand": 7.51, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Ostwald coefficient", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.92e-01", "significand": 6.92, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/3/datum/3/", "@type": "sdo:datum", "quantity": "Mass density", "quantity#": "obo:NCIT_C75762", "value": {"@id": "datapoint/3/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.082e+03", "significand": 1.082, "exponent": 3, "sigfigs": 4}}, {"@id": "datapoint/3/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/3/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.83e-02", "significand": 2.83, "exponent": -2, "sigfigs": 3}}, {"@id": "datapoint/3/datum/5/", "@type": "sdo:datum", "quantity": "Mass concentration (m/v) (1)", "quantity#": "obo:NCIT_C179798", "value": {"@id": "datapoint/3/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.2e+02", "significand": 1.2, "exponent": 2, "sigfigs": 2}}]}, {"@id": "datapoint/4/", "@type": "sdo:datapoint", "uid": "62:241:001:001:004", "conditions#": ["condition/4/"], "data": [{"@id": "datapoint/4/datum/1/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.014e+00", "significand": 1.014, "exponent": 0, "sigfigs": 4}}, {"@id": "datapoint/4/datum/2/", "@type": "sdo:datum", "quantity": "Ostwald coefficient", "value": {"@id": "datapoint/4/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.92e-01", "significand": 6.92, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/4/datum/3/", "@type": "sdo:datum", "quantity": "Mass density", "quantity#": "obo:NCIT_C75762", "value": {"@id": "datapoint/4/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.111e+03", "significand": 1.111, "exponent": 3, "sigfigs": 4}}, {"@id": "datapoint/4/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/4/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.83e-02", "significand": 2.83, "exponent": -2, "sigfigs": 3}}, {"@id": "datapoint/4/datum/5/", "@type": "sdo:datum", "quantity": "Mass concentration (m/v) (1)", "quantity#": "obo:NCIT_C179798", "value": {"@id": "datapoint/4/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.6e+02", "significand": 1.6, "exponent": 2, "sigfigs": 2}}]}, {"@id": "datapoint/5/", "@type": "sdo:datapoint", "uid": "62:241:001:001:005", "conditions#": ["condition/5/"], "data": [{"@id": "datapoint/5/datum/1/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/5/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.280e+00", "significand": 1.28, "exponent": 0, "sigfigs": 4}}, {"@id": "datapoint/5/datum/2/", "@type": "sdo:datum", "quantity": "Ostwald coefficient", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.65e-01", "significand": 6.65, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/5/datum/3/", "@type": "sdo:datum", "quantity": "Mass density", "quantity#": "obo:NCIT_C75762", "value": {"@id": "datapoint/5/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.141e+03", "significand": 1.141, "exponent": 3, "sigfigs": 4}}, {"@id": "datapoint/5/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/5/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.72e-02", "significand": 2.72, "exponent": -2, "sigfigs": 3}}, {"@id": "datapoint/5/datum/5/", "@type": "sdo:datum", "quantity": "Mass concentration (m/v) (1)", "quantity#": "obo:NCIT_C179798", "value": {"@id": "datapoint/5/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2e+02", "significand": 2.0, "exponent": 2, "sigfigs": 1}}]}, {"@id": "datapoint/6/", "@type": "sdo:datapoint", "uid": "62:241:001:001:006", "conditions#": ["condition/6/"], "data": [{"@id": "datapoint/6/datum/1/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/6/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.563e+00", "significand": 1.563, "exponent": 0, "sigfigs": 4}}, {"@id": "datapoint/6/datum/2/", "@type": "sdo:datum", "quantity": "Ostwald coefficient", "value": {"@id": "datapoint/6/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.58e-01", "significand": 6.58, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/6/datum/3/", "@type": "sdo:datum", "quantity": "Mass density", "quantity#": "obo:NCIT_C75762", "value": {"@id": "datapoint/6/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.165e+03", "significand": 1.165, "exponent": 3, "sigfigs": 4}}, {"@id": "datapoint/6/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/6/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.69e-02", "significand": 2.69, "exponent": -2, "sigfigs": 3}}, {"@id": "datapoint/6/datum/5/", "@type": "sdo:datum", "quantity": "Mass concentration (m/v) (1)", "quantity#": "obo:NCIT_C179798", "value": {"@id": "datapoint/6/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.4e+02", "significand": 2.4, "exponent": 2, "sigfigs": 2}}]}, {"@id": "datapoint/7/", "@type": "sdo:datapoint", "uid": "62:241:001:001:007", "conditions#": ["condition/7/"], "data": [{"@id": "datapoint/7/datum/1/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/7/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.835e+00", "significand": 1.835, "exponent": 0, "sigfigs": 4}}, {"@id": "datapoint/7/datum/2/", "@type": "sdo:datum", "quantity": "Ostwald coefficient", "value": {"@id": "datapoint/7/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.53e-01", "significand": 6.53, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/7/datum/3/", "@type": "sdo:datum", "quantity": "Mass density", "quantity#": "obo:NCIT_C75762", "value": {"@id": "datapoint/7/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.199e+03", "significand": 1.199, "exponent": 3, "sigfigs": 4}}, {"@id": "datapoint/7/datum/4/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/7/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.67e-02", "significand": 2.67, "exponent": -2, "sigfigs": 3}}, {"@id": "datapoint/7/datum/5/", "@type": "sdo:datum", "quantity": "Mass concentration (m/v) (1)", "quantity#": "obo:NCIT_C179798", "value": {"@id": "datapoint/7/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.8e+02", "significand": 2.8, "exponent": 2, "sigfigs": 2}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "V\u00e1zquez, G.; Chenlo, F.; Pereira, G.; Peaguda, J.; An. Quim. 1994, 90, 324-28."}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 62 (page ?) - Carbon dioxide with Potassium iodide and Water", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-63.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}