Components:

(1) Carbon dioxide, CO2; [124-38-9] NIST WebBook
(2) Calcium nitrate, Ca(NO3)2; [10124-37-5] NIST WebBook
(3) Water, H2O; [7732-18-5] NIST WebBook

Original Measurements

Onda, K.; Sada, E.; Kobayashi, T.; Kito, S.; Ito, K.; J. Chem. Eng. Jpn. 1970, 3, 18-24.

Variables:

Ambient temperature: 298.15 K
Pressure: 101.325 kPa
Amount concentration (2): C2/mol L-1 = 0 - 2.110

Prepared by:

C.L. Young

Method/Apparatus/Procedure:

Solutions made up by weight and density measured but not reported in paper. Equilibrium established between a measured volume of gas and a measured amount of gas-free liquid in a cell fitted with a magnetic stirrer. Amount of gas absorbed estimated from change in volume of gas. Details in source.

Source and Purity of Materials:
  1. Commercial sample, minimum purity 99.8 mole%.
  2. Analytical grade.
  3. Distilled and degassed.
Estimated Errors:

Ambient temperature: δT/K = ±0.2 (estimated by compiler)
Mass concentration (m/v) (1): δα = ±2% (estimated by the compiler)

Experimental Values:
Note: P = 1 atm = 101.325 kPa = 1.01325 bar
T (K) C2 (mol/L) α (cm3(g) cm-3(l) atm-1)
298.15 0.0 7.595 x 10-1
298.15 3.04 x 10-1 6.847 x 10-1
298.15 7.01 x 10-1 5.993 x 10-1
298.15 1.34 4.810 x 10-1
298.15 1.619 4.356 x 10-1
298.15 2.11 3.647 x 10-1

(a) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].

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