SDS Volume (2519)
Volume 60. Halogenated Methanes with Water, p None
Original Measurements
Johnson, J. R.; 'Self-Association and Hydration of Phenol in Several Organic Solvents' Ph.D. Dissertation, Univ. Oklahoma, Norman, OK, 1966.
Variables:
Room Temp: 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The equilibrium between tetrachloromethane and water took place in a well-stirred water bath. The experimental samples were allowed to equilibrate for two or more days. Water analyses were made with a Beckman Aquameter using a Karl Fischer reagent. The solubility of tetrachloromethane in water was measured by using a vapor pressure measuring device. Full details are available in the thesis.
Source and Purity of Materials:
- Allied Chemical Corp., purified by distillation before use.
- distilled.
Estimated Errors:
Ambient temperature: ±0.1 K.
Mass concentration (m/v) (1): ±4%.
Components:
- Tetrachloromethane, $\ce{ CCl4 }$; [56-23-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $C_{1}$ (mol/m3) | $C_{2}$ (mol/dm3) | 100w1 | 100w2 |
|---|---|---|---|---|
| 25 | 5.1 | 8.7 | 0.078 | 9.89 x 10-3 |
