SDS Volume (2424)

Volume 60. Halogenated Methanes with Water, p None

Original Measurements

Miller, M. M.; Wasik, S. P.; Huang, G. L.; Shiu, W. Y.; Mackay, D.; Environ. Sci. Technol. 1985, 19, 522-529.

Variables:

Room Temp: 298 $\pu{K}$

Prepared by:

A.L. Horvath

Method/Apparatus/Procedure:

A saturated aqueous solution was prepared by passing water through a column which was packed with glass beads coated with bromochloromethane. The saturated solution was then pumped through an extractor column and bromochloromethane was extracted into an analytical column. The samples were analyzed with a liquid chromatograph equipped with both an UV absorbance and a fluorescent detector with excitation filters. The peak area was established using a Hewlett-Packard integrator.

Source and Purity of Materials:
  1. Eastman Kodak Co., commercial quality, used as received.
  2. Double distilled.
Estimated Errors:

Ambient temperature: ±1 K (compiler).
Mass concentration (m/v) (1): Not specified.

Components:
  1. Bromochloromethane, $\ce{ CH2BrCl }$; [74-97-5] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $C_{1}$ (mol/m3) 100w1 $x_{1}$
25 129.0 1.6462.325 x 10-3

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