SDS Volume (2328)
Volume 60. Halogenated Methanes with Water, p None
Original Measurements
Herz, W.; Ber. Dtsch. Chem. Ges. 1898, 31, 2669-72.
Variables:
Room Temp: 295 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The mutual solubility between trichloromethane and water was determined by a volumetric method at constant temperature. The change in the volume upon mixing was measured in a calibrated cylinder. The specific weight of the pure components and the solutions were also determined.
Source and Purity of Materials:
- Source and purity not given, $d_{4}$ = 1.4760 g mL-1 at 22°C.
- Distilled (compiler), $d_{4}^{22}$ = 0.9980.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): Not specified.
Components:
- Trichloromethane, $\ce{ CHCl3 }$; [67-66-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100V1/V2 | 100V2/V1 | 100w1 | 100w2 |
|---|---|---|---|---|
| 22 | 0.420 | 0.152 | 0.620 | 0.102 |


