{"compilation": {"title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Trichloromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Herz, W.; Ber. Dtsch. Chem. Ges. 1898, 31, 2669-72.", "pubtype": "paper", "url": "https://doi.org/10.1002/cber.18980310317"}], "system": "Trichloromethane with Water", "substances": [{"constituent": 1, "name": "Trichloromethane", "formula": "CHCl3", "molweight": 119.378, "casrn": "67-66-3", "inchi": "InChI=1S/CHCl3/c2-1(3)4/h1H", "inchikey": "HEDRZPFGACZZDS-UHFFFAOYSA-N", "sample": "Source and purity not given, $d_{4}$ = 1.4760 g mL-1 at 22°C."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled (compiler), $d_{4}^{22}$ = 0.9980."}], "method": "The mutual solubility between trichloromethane and water was determined by a volumetric method at constant temperature. The change in the volume upon mixing was measured in a calibrated cylinder. The specific weight of the pure components and the solutions were also determined.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.2e+01", "significand": "2.2", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Percent relative volume ratio (1/2)", "number": "4.20e-01", "significand": "4.20", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Percent relative volume ratio (2/1)", "number": "1.52e-01", "significand": "1.52", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "6.20e-01", "significand": "6.20", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Percent mass fraction (2)", "number": "1.02e-01", "significand": "1.02", "exponent": "-1", "sigfigs": "3", "unit": "1"}]}]}]}}