SDS Volume

Volume 60. Halogenated Methanes with Water, p None

Source Publication

Mackay, D.; Shiu, W.; Bobra, A.; Billington, J.; Chau, E.; Volatilization of Organic Pollutants from Water, U.S. EPA Report 600/3-82-019, Washington, DC, 1982, (NTIS PB82230939).

Conditions:

Room Temp: 298 $\pu{K}$

Compiler:

A.L. Horvath

Methodology:

An aqueous solution with an excess of tribromomethane was stirred for one day before being introduced into a 1 L glass vessel. Nitrogen entered at the bottom of the vessel through a sintered glass disk. The exit gas flow rate was measured by a soap bubble flow meter. The concentration of tribromomethane in water was determined by gas chromatography. The GC was equipped with both dual flame ionization detector and an electron capture detector.

Sample Information:
  1. Source and purity not given.
  2. doubly distilled.
Measurement Errors:

Ambient temperature: ±1.0 K.
Mass concentration (m/v) (1): Not specified.

System Components:
  1. Tribromomethane, $\ce{ CHBr3 }$; [75-25-2] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $x_{2}$ $x_{2}$ $C_{1}$ (mol/m3) 100w1 a 100w2 $x_{1}$
25 1.0 x 10-31.0 x 10-312.0 0.30327.14 x 10-32.168 x 10-4

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