{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/2316/jsonld#"}], "@id": "", "generatedAt": "10-20-26 14:45:08", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/2316/jsonld#", "@type": "sdo:scidataFramework", "uid": "60_137", "title": "Solubility data from IUPAC SDS Volume 60 (page ?) - Tribromomethane with Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Ari L. Horvath", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afq:AFQ_0000168", "afrl:0000269", "afrl:0000270", "obo:NCIT_C25206", "qudt:DEG_C", "sdo:numericvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "An aqueous solution with an excess of tribromomethane was stirred for one day before being introduced into a 1 L glass vessel. Nitrogen entered at the bottom of the vessel through a sintered glass disk. The exit gas flow rate was measured by a soap bubble flow meter. The concentration of tribromomethane in water was determined by gas chromatography. The GC was equipped with both dual flame ionization detector and an electron capture detector.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Tribromomethane", "formula": "CHBr3", "casrn": "75-25-2", "iupacname": "bromoform", "inchikey": "DIKBFYAXUHHXCS-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Tribromomethane", "description": "Source and purity not given.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Water", "description": "doubly distilled.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Tribromomethane with Water", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Degree celsius", "unit#": "qudt:DEG_C"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.5e+01", "significand": 2.5, "exponent": 1, "sigfigs": 2}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "60:137:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.0e-03", "significand": 1.0, "exponent": -3, "sigfigs": 2}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.0e-03", "significand": 1.0, "exponent": -3, "sigfigs": 2}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Amount concentration (1)", "quantity#": "afq:AFQ_0000168", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.20e+01", "significand": 1.2, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/1/datum/4/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/1/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.032e-01", "significand": 3.032, "exponent": -1, "sigfigs": 4}}, {"@id": "datapoint/1/datum/5/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/1/datum/5/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.14e-03", "significand": 7.14, "exponent": -3, "sigfigs": 3}}, {"@id": "datapoint/1/datum/6/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/6/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.168e-04", "significand": 2.168, "exponent": -4, "sigfigs": 4}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Mackay, D.; Shiu, W.; Bobra, A.; Billington, J.; Chau, E.; Volatilization of Organic Pollutants from Water, U.S. EPA Report 600/3-82-019, Washington, DC, 1982, (NTIS PB82230939).", "url": "https://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=9101XY1F.txt"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 60 (page ?) - Tribromomethane with Water", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-60.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}