SDS Volume
Volume 60. Halogenated Methanes with Water, p None
Source Publication
Glasoe, P. K.; Schultz, S. D.; J. Chem. Eng. Data 1972, 17, 66-8.
Conditions:
Room Temp: 288 - 308 $\pu{K}$
Compiler:
Methodology:
The saturation of heavy water with tetrachloromethane was done in a closed system, protected from atmospheric moisture, and placed in a constant temperature water bath. The solubility of heavy water in tetrachloromethane was measured using the Karl Fischer titration method with a 'dead stop' end-point determination [1]. 15 Trials were done at each temperature.
Sample Information:
- Source not given, 99.8% pure, used as received.
- Source not given. Reagent grade, purified by distillation before use.
Measurement Errors:
Ambient temperature: ±0.1 K (compiler).
Mass concentration (m/v) (1): See above.
Methodology Citation
1 Wernimont, G.; Hopkinson, F. J. Ind. Eng. Chem., Anal. Ed. 1943, 272.
System Components:
- Water-d2, $\ce{ D2O }$; [7789-20-0] NIST WebBook
- Tetrachloromethane, $\ce{ CCl4 }$; [56-23-5] NIST WebBook
Experimental Data
| $T$ (°C) | $C_{1}$ (mol/m3) | 100w1 a | $x_{1}$ a |
|---|---|---|---|
| 15 | 5.7 | 7.13 x 10-3 | 5.47 x 10-4 |
| 25 | 7.5 | 9.49 x 10-3 | 7.28 x 10-4 |
| 30 | 8.4 | 0.0107 | 8.21 x 10-4 |
| 35 | 10.3 | 0.0132 | 1.013 x 10-3 |
