Compilation - 1,4-Dichlorobenzene with Water (IUPAC SDS Volume 20)
SDS Volume (218)
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 113
Original Measurements
Aquan-Yuen, M.; Mackay, D.; Shiu, W. Y.; J. Chem. Eng. Data 1979, 24, 30-4.
Variables:
Room Temp: 25 °C
Prepared by:
Method/Apparatus/Procedure:
Saturated solution was prepared by adding an excess of solute to water in a closed flask with standing for 24 hours. Then, the sample was allowed to settle at 25 °C in a thermostat bath for at least 48 hours before analysis. The solubility was determined by solvent extraction followed by gas chromatographic analysis using a Hewlett Packard Model 5750 apparatus (equipped with a flame ionization detector and a 10 ft stainless steel column packed with 10% SE 30 ultraphase on high performance Chromosorb P, 60/80 mesh).
Source and Purity of Materials:
- Commercial product (BDH), evidently used as received.
- Source and purity not specified.
Estimated Errors:
Ambient temperature: ±0.2 K (compiler).
Mass concentration (m/v) (1): ±3% (authors, the value is based on the std. error of the least squares fit on the solubility of 1,4-dichlorobenzene in water and aqueous electrolyte solutions.
Components:
- 1,4-Dichlorobenzene, $\ce{ C6H4Cl2 }$; [106-46-7] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | $C_{1}$ (mol/dm3) |
|---|---|---|
| 25 | 1.0713 x 10-5 | 5.9283 x 10-4 |
(b) Calculated by F. W. Getzen.
(a) Reported.
