Compilation - Ethene with Water (IUPAC SDS Volume 57)
SDS Volume (1170)
Volume 57. Ethene, p None
Original Measurements
Sanchez, M.; Lentz, H.; High Temp. High Press. 1973, 5, 689-699.
Variables:
Room Temp:
439.15 - 573.15
$\pu{K}$
Pressure:
10.0 - 94.5
$\pu{MPa}$
Prepared by:
Method/Apparatus/Procedure:
The apparatus consisted of a high pressure piston pump, Bourdon pressure gauges, a stainless steel capillary tube equilibrium cell 4.7 mm in inside diameter, a tubular storage chamber for the gas, as well as an associated temperature sensing element, sampling probes and valves. The apparatus was mounted in a constant temperature chamber. The equilibrium cell was charged with a known quantity of solvent by rotating it to a horizontal position. The quantity of gas was determined by material balance and the PV relation in the gas supply tube.
Source and Purity of Materials:
- Ethene purity was specified to be 99.99%.
- Water was double distilled.
Estimated Errors:
Ambient temperature: δT/K = ±0.5
Mass concentration (m/v) (1): δx1/x1 = ±0.05 or ±5% (Compiler)
Components:
- Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Smoothed values as obtained by extrapolation and interpolation are also available in this paper.
| $T$ ($\pu{K}$) | $T$ (°C) | $y_{1}$ | $x_{1}$ | $P$ ($\pu{bar}$) | $P_{\rm{c}}$ ($\pu{MPa}$) |
|---|---|---|---|---|---|
| 439.15 | 166 | 0.860 | 4 x 10-3 | 1E+2 | 8.60 |
| 439.15 | 166 | 0.890 | 5 x 10-3 | 1.5E+2 | 13.35 |
| 439.15 | 166 | 0.959 | 0.010 | 635 | 60.90 |
| 439.15 | 166 | 0.910 | 8 x 10-3 | 945 | 86.00 |
| 523.15 | 250 | 0.630 | 0.014 | 1.9E+2 | 11.97 |
| 523.15 | 250 | 0.688 | 0.018 | 2.4E+2 | 16.51 |
| 523.15 | 250 | 0.766 | 0.026 | 375 | 28.73 |
| 523.15 | 250 | 0.750 | 0.034 | 5.7E+2 | 42.75 |
| 523.15 | 250 | 0.810 | 0.040 | 7.3E+2 | 59.13 |
| 573.15 | 300 | 0.516 | 0.024 | 2.4E+2 | 12.38 |
| 573.15 | 300 | 0.597 | 0.036 | 3.8E+2 | 22.69 |
| 573.15 | 300 | 0.550 | 0.047 | 5.5E+2 | 30.25 |
(a) Calculated by the compiler.
(b) Bracketed () in original paper.
