Evaluator
Adam Skrzecz Institute of Physical Chemistry, Polish Academy of Sciences
Evaluation
A survey of reported compositions along the saturation curve (sat), and compositions of coexisting phases in equilibrium (eq.) for the system 2-methyl-2-propanol-benzene-water is given in Table 69.

Saturation curve
The ternary system 2-methyl-2-propanol-benzene-water forms a miscibility gap of type 1. Only one binary system benzene-water forms a miscibility gap. These binary data were compiled and critically evaluated in a previously published SDS volume, Ref. 3. The recommended values of mutual solubility at 298 K are x'2=0.9970, x"2=0.000 409. The mutual solubility of benzene and water was also reported by Simonsen and Washburn,1 (x'2=0.9970, x"2=0.0003); these are consistent with the recommended values. Letcher et al.2 reported data only in graphical form. Therefore these data are not compiled. The plait point estimated by Letcher and Siswana4 was x1=0.16 and x2=0.02, while the maximum alcohol concentration on the binodal curve is x1=0.41. This point is consistent with the results of Simonsen and Washburn measurements, x1=0.38.1 The experimental tie lines at 298.2 K1 are presented in Fig. 36 together with the experimental points along the saturation curve.
Figure
Solubility graph
Sources:

1 Simonsen, D. R.; Washburn, E. R.; J. Am. Chem. Soc. 68, 235 (1946).
2 Letcher, T. M.; Sewry, J.; Radloff, S.; S. Afr. J. Chem. 43, 56 (1990).
3 Shaw, D. G.; 'Hydrocarbons with Water and Seawater, Part I: Hydrocarbons C5 to C7' IUPAC Solubility Data Series, 1989, Vol. 37, Pergamon Press.
4 Letcher, T. M.; Siswana, P. M.; Fluid Phase Equilib. 74, 203 (1992).