Evaluator
Adam Skrzecz Institute of Physical Chemistry, Polish Academy of Sciences
Evaluation
A survey of reported compositions along the saturation curve (sat), and compositions of coexisting phases in equilibrium (eq.) for the system 2-methyl-1-propanol-benzene-water is given in Table 66.

Saturation curve
The ternary system 2-methyl-1-propanol-benzene-water forms a miscibility gap of type 2. Two binary systems, benzene-water and 2-methyl-1-propanol-water, form miscibility gaps. These binary systems were compiled and critically evaluated in previously published SDS volumes, Refs. 3 and 4, respectively. These recommended values of mutual solubility at 298 K are x'2=0.9970, x"2=0.000 409 for benzene-water system, and x'1=0.548, x=0.021 for 2-methyl-1-propanol-water system. The tie lines and experimental points along the saturation curve reported by Alberty and Washburn1 are consistent with one another. The reported mutual solubility of the 2-methyl-1-propanol-water system x'1=0.5425 and x"1=0.0208 are in good agreement with the recommended values. Data of Letcher et al.2 were reported in graphical form only and therefore are not compiled. The maximum alcohol concentration on the binodal curve at 298 K, x1=0.55,1 is consistent with the results of Alberty and Washburn,1 x1=0.558. The experimental tie lines at 298.2 K, Ref. 1, are presented in Fig. 34 together with the experimental points along the saturation curve.
Figure
Solubility graph
Sources:

2 Letcher, T. M.; Sewry, J.; Radloff, S.; S. Afr. J. Chem. 43, 56 (1990).
3 Shaw, D. G.; 'Hydrocarbons with Water and Seawater, Part I: Hydrocarbons C5 to C7' IUPAC Solubility Data Series, 1989, Vol. 37, Pergamon Press.
4 Barton, A. F. M.; ed.; Solubility Data Series, Vol. 15, Alcohols with Water (Pergamon, New York 1984).
1 Alberty, R. A.; Washburn, E. R.; J. Phys. Chem. 49, 4 (1945).