SDS Volume

Volume 38. Hydrocarbons in Water and Seawater, Part II, p None

Source Publication

Davis, W. W.; Krahl, M. E.; Cloves, G. H. A.; J. Am. Chem. Soc. 1942, 64, 108-10.

Conditions:

Room Temp: 27 °C

Compiler:

M.C. Haulait-Pirson

Methodology:

The method consisted of preparing serial dilutions of a suspension of [1] in [2] and determining nephelometrically the amount of [1] per unit volume beyond which further dilution caused no reduction in light scattering, which remained equal to that of pure [2]. A Bausch and Lomb Dubosque colorimeter model 100-mm was employed. Many details are reported in [1].

Sample Information:
  1. Eastman Kodak Company, 599; MP range 100.0-100.9°C; used as received; [2].
  2. Dust-free.
Measurement Errors:

Ambient temperature: ±3°C
Mass concentration (m/v) (1): ±0.05 × 10-3 g(1) dm-3 (2)

Methodology Citations

1 Davis, W. W.; Parker Jr., T. V.; J. Am. Chem. Soc. 1942, 64, 101.
2 Davis, W. W.; Krahl, M. E.; Cloves, G. H. A., J. Am. Chem. Soc. 1940, 62, 3086.

System Components:
  1. Phenanthrene, $\ce{ C14H10 }$; [85-01-8] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data

The best value recommended by the authors is 1.60× 10-3 g(1) L-1 (2).
Assuming that 1.00 L sln = 1.00 kg sln, the corresponding mass percent and mole fraction calculated by the compiler are 1.60 × 10-4 g(1)/100 g sln and 1.62 × 10-7.

$T$ (°C)
27
27
27

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