SDS Volume
Volume 38. Hydrocarbons in Water and Seawater, Part II, p None
Source Publication
May, W. E.; Wasik, S. P.; Freeman, D. H.; Anal. Chem. 1978, 50, 997-1000
Conditions:
Room Temp: 5.2 - 29.0 °C
Compiler:
Methodology:
The dynamic coupled column liquid chromatography (DCCLC) method was based on generating saturated solutions by pumping water through a column packed with glass beads that have been coated with the component [1] (generator column). The concentration of [1] in the effluent of the generator column was measured by a modification of the coupled column liquid chromatographic process that has been described in [1].
Sample Information:
- Commercial product; less than 3% impurities.
- Distilled over $\ce{KMnO4}$ and $\ce{NaOH}$ and passed through a column packed with XAD-2 (Rohm and Hass, Philadelphia, Pa.)
Measurement Errors:
Ambient temperature: ±0.05°C
Mass concentration (m/v) (1): stand. dev. See above
Methodology Citation
System Components:
- Anthracene, $\ce{ C14H10 }$; [120-12-7] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
ug(1)/kg(2) = 8.21 + 0.8861 t + 0.0097 t2 + 0.0013 t3
| $T$ (°C) | Rm1:2 ($\pu{\upmu g(\rm{1})/kg(\rm{2})}$) | $x_{1}$ | MR1 (g1/100 g sln) |
|---|---|---|---|
| 5.2 | 12.7 | 1.28 x 10-9 | 1.27 x 10-6 |
| 10.0 | 17.5 | 1.77 x 10-9 | 1.75 x 10-6 |
| 14.1 | 22.2 | 2.24 x 10-9 | 2.22 x 10-6 |
| 18.3 | 29.1 | 2.94 x 10-9 | 2.91 x 10-6 |
| 22.4 | 37.2 | 3.76 x 10-9 | 3.72 x 10-6 |
| 24.6 | 43.4 | 4.39 x 10-9 | 4.34 x 10-6 |
| 25.0 | 44.6 | 4.51 x 10-9 | 4.46 x 10-6 |
| 28.7 | 55.7 | 5.63 x 10-9 | 5.57 x 10-6 |
| 29.0 | 57.0 | 5.76 x 10-9 | 5.7 x 10-6 |
