Compilation - Iodobenzene with Water (IUPAC SDS Volume 20)
SDS Volume (88)
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 215
Original Measurements
Andrews, L. J.; Keefer, R. M.; J. Am. Chem. Soc. 1950, 72(7), 3113-6.
Variables:
Room Temp: 25.0 °C
Prepared by:
Method/Apparatus/Procedure:
Water was saturated with iodobenzene in a glass-stoppered Erlenmeyer flask rotated in a constant temperature bath for 20 hours. The saturated solution was extracted with n-hexane for analysis. The optical density of the extract was measured against a n-hexane standard using a Beckman spectrophotometer [1].
Source and Purity of Materials:
- Eastman Kodak Co., commercial reagent, BP = 188.3°C, fractionated before use. 2. Not specified.
Estimated Errors:
Ambient temperature: ±0.1 K. (compiler).
Mass concentration (m/v) (1): ±10% (compiler).
References
1 Andrews, L. J.; Keefer, R. M.; J. Am. Chem. Soc. 1949, 71, 3644-77.
Components:
- Iodobenzene, $\ce{ C6H5I }$; [591-50-4] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | $C_{1}$ (mol/dm3) | Cm1 (g/dm3) |
|---|---|---|---|
| 25.0 | 1.59 x 10-5 | 8.82 x 10-4 | 0.18 |
(a) Reported.
(b) Calculated by F. W. Getzen.
(c) Calculated by the compiler.
