SDS Volume (871)

Volume 38. Hydrocarbons in Water and Seawater, Part II, p None

Original Measurements

Eganhouse, R. P.; Calder, J. A.; Geochim. Cosmochim. Acta 1976, 40, 555-61.

Variables:

Room Temp: 25 °C

Prepared by:

A. Maczynski

Method/Apparatus/Procedure:

A mixture of 500 mL (2) and 0.001 mol (1) was equilibrated in an Erlenmeyer flask for 12 h (agitation) + 24 h (stationary). The saturated solution, 100 mL was extracted with hexane, concentrated by evaporation under nitrogen and analyzed by glc. A 5700 A Hewlett-Packard instrument equipped with dual compensating columns and flame ionization detectors was employed.

Source and Purity of Materials:
  1. source not specified; analytical grade; used as received; no impurities by glc.
  2. doubly distilled; free of trace organics.
Estimated Errors:

Ambient temperature: ±0.5°C
Mass concentration (m/v) (1): ±0.1 mg(1)/kg(2) (from eight determinations)

Components:
  1. 2-Ethylnaphthalene, $\ce{ C12H12 }$; [939-27-5] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data

The solubility of 2-ethylnaphthalene in water at 25°C was reported to be 8.00 mg(1)/kg(2) and 5.1 × 10-5 mol(1) dm-3(2).
The corresponding mass percent and mole fraction, x1, calculated by the compiler are 8.00 × 10-4 g(1)/100 g sln and 9.22 × 10-7.

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