Compilation - Styrene with Water (IUPAC SDS Volume 38)
SDS Volume (752)
Volume 38. Hydrocarbons in Water and Seawater, Part II, p None
Original Measurements
Lane, W. H.; Ind. Eng. Chem. Anal. Ed. 1946, 18, 295-6.
Variables:
Room Temp: 7 - 65 °C
Prepared by:
Method/Apparatus/Procedure:
(a) The solubility of (1) in (2) was determined by means of the formaldehyde-sulfuric acid reagent, (1). The value shown for 7 °C is the mean of three determinations, and the value for 25 °C is the mean of two determinations; all other data are single determinations only.
(b) The cloud point exhibited by this system appeared to be very sharp, as the samples passed from a state in which they were cloudy within 1 °C. The cloud point data averages of from two to eight separate determinations. Cloud points at 0.025 g(1)/100 g solution were very faint.
Source and Purity of Materials:
- Source not specified; fresh samples; used as received.
- not specified.
Estimated Errors:
Ambient temperature: (b) ±0.5°C (from two to eight determinations)
References
1 Morris, H. E.; Stiles, R. B.; Lane, W. H.; Ind. Eng. Chem. Anal. Ed. 1946, 18, 294.
Components:
- Styrene, $\ce{ C8H8 }$; [100-42-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
(a) Formaldehyde-Sulfuric Acid Reagent Method
| $T$ (°C) | MR1 (g1/100 g2) | $x_{1}$ |
|---|---|---|
| 7 | 0.029 | 5.0 x 10-5 |
| 24 | 0.033 | 5.7 x 10-5 |
| 32 | 0.036 | 6.2 x 10-5 |
| 40 | 0.040 | 6.9 x 10-5 |
| 51 | 0.045 | 7.8 x 10-5 |
| 15 | 0.025 | 4.3 x 10-5 |
| 25 | 0.031 | 5.3 x 10-5 |
| 44 | 0.040 | 6.9 x 10-5 |
| 49 | 0.045 | 7.8 x 10-5 |
| 56 | 0.050 | 8.6 x 10-5 |
| 65 | 0.058 | 1.00 x 10-4 |
