NIST-IUPAC Solubility Data Series

3-Chlorophenol with Water (IUPAC SDS Volume 20)

SDS Volume

Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 191

Source Publication

Sidgwick, N. V.; Turner, S. L.; J. Chem. Soc. 1922, 121, Part II, 2256-63.

Conditions:

Room Temp: -17.0 - 130.8 °C

Compiler:

A. Vesala

Methodology:

The solubility versus temperature measurements were made by the so called synthetic method which involved the mixing of known masses of solute and solvent and the testing of miscibility with temperature. A bracketing procedure was applied. In this method, two adjustable thermostats, one above and the other below the solubility temperature, were used. The contents of sample tubes in the two thermostat baths were observed to maintain one homogeneous and the other heterogeneous as the temperature interval between the two thermostats was reduced by successive steps.

Sample Information:

Synthesized from 1-chloro-3-nitrobenzene by reduction and diazotisation. MP = 32.5°C.
No specifications given.

System Components:

3-Chlorophenol, $\ce{ C6H5ClO }$; [108-43-0] NIST WebBook
Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook

Experimental Data

$T$ (°C)	$x_{1}$	M^R₁ (g/kg)	m₁ (mol/kg)
-17.0	0.62455^b	922.3^a	7.1743^b
-13.2	0.60852^b	917.3^a	7.1354^b
-8.2	0.56080^b	901.1^a	7.0093^b
-4.8	0.52282^b	886.6^a	6.8966^b
-0.9	0.44012^b	848.7^a	6.0617^b
-0.18	1.03 x 10^-3^b	7.3^a	0.0568^b
1.2	1.771 x 10^-3^b	12.5^a	0.09723^b
2.5	2.635 x 10^-3^b	18.5^a	0.1439^b
3.2	0.44012^b	848.7^a	6.6017^b
4.5	0.48819^b	871.9^a	6.7822^b
10.8	0.62455^b	922.3^a	7.1742^b
11.8	0.40455^b	829.0^a	6.4485^b
17.0	0.73117^b	951.0^a	7.3975^b
22.2	0.82484^b	971.1^a	7.5538^b
23.1	0.39453^b	823.0^a	6.4018^b
32.5	1.0^b	1.0000 x 10³^a	7.7787^b
85.25	7.506 x 10^-3^b	51.2^a	0.3983^b
109.8	0.25759^b	712.3^a	5.5407^b
118.0	0.017248^b	111.3^a	0.86576^b
123.0	0.021511^b	135.6^a	1.0548^b
127.5	0.029531^b	178.4^a	1.3877^b
129.1	0.14955^b	556.5^a	4.3288^b
130.5	0.10711^b	461.2^a	3.5875^b
130.7	0.081882^b	388.9^a	3.0251^b
130.8	0.061922^b	320.2^a	2.4097^b

(a) Reported.

(b) Calculated by F. W. Getzen.

Figure 1. 3-chlorophenol in water solubility behavior versus centigrade temperature

IUPAC-NIST Solubility Data Series, SRD 106