SDS Volume
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 179
Source Publication
Nelson, H. D.; Smit, J. H.; S. Afr. Tydskr. Chem. 1978, 31(2), 76.
Conditions:
Room Temp: 5 - 45 °C
Compiler:
Methodology:
Water was saturated with chlorobenzene from the vapor phase in a special flask [1] placed in a thermostat bath using a shaker for a 24 hour equilibration period. A gas chromatographic analysis was done by sample injection into a 1.5 m stainless steel column having a 5% Apiezon M coating on Celite operated at 120 °C. The chromatograph was fitted with a flame ionization detector. Three samples from each flask were analyzed.
Sample Information:
- Not specified.
- Not specified.
Measurement Errors:
Ambient temperature: ±0.1 K (compiler).
Mass concentration (m/v) (1): ±2.9% (compiler).
Methodology Citation
1 Nelson, H. D.; De Ligny, C. L.; Recl. Trav. Chim. Pays-Bas 1968, 87, 528-44.
System Components:
- Chlorobenzene, $\ce{ C6H5C1 }$; [108-90-7] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | MR1 (g/kg) | m1 (mol/kg) |
|---|---|---|---|
| 5 | 6.4 x 10-6c | 0.0400a | 3.55 x 10-4b |
| 25 | 1.71 x 10-5c | 0.1068a | 9.492 x 10-4b |
| 35 | 4.28 x 10-5c | 0.2674a | 2.376 x 10-3b |
| 45 | 6.41 x 10-5c | 0.4005a | 3.558 x 10-3b |
(a) Calculated by the compiler.
(b) Calculated by F. W. Getzen.
(c) Reported.
