SDS Volume

Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 178

Source Publication

Kirchnerová, J.; Cave, G. C. B.; Can. J. Chem. 1976, 54(24), 3909-16.

Conditions:

Room Temp: 25 °C

Compiler:

A.L. Horvath

Methodology:

A mixture of 50 mL chlorobenzene and 6 mL water in a bottle was submerged in a water thermostat bath for two days. The concentration of the water in the organic phase was determined by a conventional Karl Fischer dead stop back titration. Determinations were done in triplicate. A detailed description of the complex experimental procedure has been included in a Ph.D. dissertation [1].

Sample Information:

1. Distilled and deionized.
2. Fischer - B255, washed with cc. $\ce{H2SO4}$ and $\ce{K2CO3}$ solutions and distilled water. Dried over silica gel and fractionally distilled, purity: 99.8%.

Measurement Errors:

Ambient temperature: ±0.1 K.
Mass concentration (m/v) (1): ±1%.

Methodology Citation

¹ Kirchnerova, J.; Ph. D. Thesis, McGill Univ.; Montreal, Quebec, April 1975, 280 pp.