Compilation - 2-Methyl-1,3-butadiene with Water (IUPAC SDS Volume 37)
SDS Volume (619)
Volume 37. Hydrocarbons in Water and Seawater, Part I, p 10
Original Measurements
Pavlova, S. P.; Pavlov, S. Yu.; Serafimov, L. A.; Kofman, L. S.; Promyshlennost. Sinteticheskogo Kauchuka 1966, 3, 18-20.
Variables:
Room Temp: 20 - 60 °C
Prepared by:
Method/Apparatus/Procedure:
The solubility of (1) in (2) was determined by glc. The solubility of (2) in (1) was determined by the Karl Fischer reagent method.
Source and Purity of Materials:
- source not specified; better than 99.7 wt%.
- Doubly distilled.
Estimated Errors:
Ambient temperature: ±0.1 K
Components:
- 2-Methyl-1,3-butadiene, $\ce{ C5H8 }$; [78-79-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Solubility of 2-methyl-1,3-butadiene in water
| $T$ (°C) | $x_{1}$ | MR1 (g1/100 g sln) |
|---|---|---|
| 20 | 1.441 x 10-4 | 0.05448 |
| 40 | 1.758 x 10-4 | 0.06646 |
| 50 | 2.013 x 10-4 | 0.07609 |
| 60 | 2.294 x 10-4 | 0.08671 |
