Components:

(1) Pentane, C5H12; [109-66-0] NIST WebBook
(2) Sodium chloride, NaCl; [7647-14-5] NIST WebBook
(3) Water, H2O; [7732-18-5] NIST WebBook

Original Measurements

Price, L. C.; Am. Assoc. Petrol. Geol. Bull. 1976, 60, 213-44.

Variables:

Ambient temperature: One temperature: 25 °C
Salinity: 1 - 360 g(2)/kg sln

Prepared by:

M. Kleinschmidt, D.G. Shaw

Method/Apparatus/Procedure:

Details given in the source. (1) was equilibrated with NaCl solution for one month. An aliquot was analyzed directly by gas chromatography.

Source and Purity of Materials:
  1. Commercial, 99+% pure
Estimated Errors:

Ambient temperature: ±1 K
Mass concentration (m/v) (1): ±10 relative%

References

1 Lyman, J.; Fleming, R. H.; J. Mar. Res. 1940, 3, 135.

Experimental Values:
Solubility of Pentane in Aqueous NaCl
T (°C) MR1 (g1/100 g2) MR2 (g/kg) x1
25.0 3.68 x 10-3 1.002 9.19 x 10-6
25.0 3.45 x 10-3 10.0 8.67 x 10-6
25.0 2.76 x 10-3 34.472 7.05 x 10-6
25.0 2.26 x 10-3 50.03 5.84 x 10-6
25.0 1.09 x 10-3 125.1 2.95 x 10-6
25.0 5.91 x 10-4 199.9 1.67 x 10-6
25.0 2.64 x 10-4 279.8 7.77 x 10-7
25.0 2.01 x 10-4 358.7 6.14 x 10-7

(a) Artificial seawater, composition not specified but probably similar to ref 1.

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