Compilation - Chlorobenzene with Water (IUPAC SDS Volume 20)
SDS Volume (58)
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 174
Original Measurements
Chey, W.; Calder, G. V.; J. Chem. Eng. Data 1972, 17(2), 199-200.
Variables:
Room Temp: 21 °C
Prepared by:
Method/Apparatus/Procedure:
A 1 to 50 volume ratio solute/solvent mixture was stirred in a separatory funnel for 20 hr in a thermostat bath. Then, the solution was passed through a separation column of nonpolar resin. The solute was eluted with isopropyl ether. Traces of water were removed using molecular sieve pellets, and the sample was injected into a gas chromatograph fitted with a stainless steel column packed with Chromosorb having a liquid phase of Carbowax for analysis. The determination was done in duplicate.
Source and Purity of Materials:
- Source not specified, Analytical Reagent grade.
- Distilled.
Estimated Errors:
Ambient temperature: ±1 K.
Mass concentration (m/v) (1): ±2%.
Components:
- Chlorobenzene, $\ce{ C6H5C1 }$; [108-90-7] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | MR1 (g/kg) | m1 (mol/kg) |
|---|---|---|---|
| 21 | 8.546 x 10-5 | 0.534 | 4.742 x 10-3 |
(a) Reported.
(b) Calculated by F. W. Getzen.
(c) Calculated by the compiler.
