Compilation - Chlorobenzene with Water (IUPAC SDS Volume 20)
SDS Volume (55)
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 172
Original Measurements
Jones, J. R.; Monk, C. B.; J. Chem. Soc. 1963, 2633-5.
Variables:
Room Temp: 25 - 35 °C
Prepared by:
Method/Apparatus/Procedure:
Tritiated water was shaken with bromobenzene in 1:10 volume ratios for 4 hours in a flask in a water thermostat bath. The water content was determined by tritium assay. The count rates were determined using a typical liquid scintillator solution technique.
Source and Purity of Materials:
- Tritiated.
- Source not known, laboratory grade, dried over CaC $\ce{I2}$ and fractionally distilled before use.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): ±5%.
Components:
- Chlorobenzene, $\ce{ C6H5C1 }$; [108-90-7] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | S1:2 | $C_{1}$ (mol/dm3) |
|---|---|---|---|
| 25 | 1.92 x 10-3 | 0.34 | 0.0188 |
| 30 | 2.239 x 10-3 | 0.395 | 0.02182 |
| 35 | 2.62 x 10-3 | 0.46 | 0.0254 |
(a) Reported.
(b) Calculated by F. W. Getzen.
(c) Calculated by the compiler.
