SDS Volume (529)

Volume 37. Hydrocarbons in Water and Seawater, Part I, p 467

Original Measurements

Price, L. C.; Am. Assoc. Petrol. Geol. Bull. 1976, 60, 213-44.

Variables:

Room Temp: 25 °C

Prepared by:

M.C. Haulait-Pirson

Method/Apparatus/Procedure:

The solubility was determined at laboratory temperatures by use of screw-cap test tubes. The (1) phase floated on top of the water and insured saturation of the (2) phase in 2 to four days. Analyses were carried out by GLC using a Hewlett-Packard model 5751 gas chromatograph with dual-flame ionization detectors. Many details are given in the paper.

Source and Purity of Materials:
  1. Phillips petroleum Company; Chemical Samples Company or Aldrich Chemical Company; 99+%.
  2. Distilled.
Estimated Errors:

Ambient temperature: ±1 K
Mass concentration (m/v) (1): ±0.02 mg(1)/kg(2)

Components:
  1. 2,3-Dimethylpentane, $\ce{ C7H16 }$; [565-59-3] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data

The solubility of 2,3-dimethylpentane in water at 25°C and at system pressure was reported to be 5.25 mg(1)/kg(2). The corresponding mass percent and mole fraction, x1, calculated by the compiler are 5.25 × 10-4 g(1)/100 g sln and 9.43 × 10-7.

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