Compilation - Chrysene with Pyrene (IUPAC SDS Volume 58)
SDS Volume (5229)
Volume 58. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part I Solutes A-E, p 295
Original Measurements
Kravchenko, V. M.; Pastukhova, I. S.; Proc. Acad. Sci. USSR; Sect. Chem. 1956, 111, 667-669.
Variables:
Temperature: 408.2 - 528.2 K
Prepared by:
Method/Apparatus/Procedure:
Phase diagram was determined using a thermal analysis method [1], supplemented by visual observation.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper, was recrystallized before use.
- Purity and chemical source were not specified in paper, was recrystallized before use.
Experimental Data
Pyrene with Chrysene
Components:
(1) Chrysene,
$\ce{ C18H12 }$;
[218-01-9]
NIST WebBook
(2) Pyrene,
$\ce{ C16H10 }$;
[129-00-0]
NIST WebBook
Experimental Values:
| T (K) | x1 | x2 |
|---|---|---|
| 423.2 | 0.0 | 1.0 |
| 413.7 | 9.9 x 10-2 | 9.01 x 10-1 |
| 410.2 | 1.36 x 10-1 | 8.64 x 10-1 |
| 408.2 | 1.65 x 10-1 | 8.35 x 10-1 |
| 415.4 | 1.87 x 10-1 | 8.13 x 10-1 |
| 420.6 | 2.10 x 10-1 | 7.90 x 10-1 |
| 441.2 | 3.03 x 10-1 | 6.97 x 10-1 |
| 458.7 | 3.98 x 10-1 | 6.02 x 10-1 |
| 473.2 | 4.95 x 10-1 | 5.05 x 10-1 |
| 487.2 | 6.04 x 10-1 | 3.96 x 10-1 |
| 496.2 | 6.86 x 10-1 | 3.14 x 10-1 |
| 506.7 | 7.82 x 10-1 | 2.18 x 10-1 |
| 517.7 | 8.97 x 10-1 | 1.03 x 10-1 |
| 528.2 | 1.0 | 0.0 |
